K. J. Ciuffi, H. C. Sacco, J. C. Biazzotto, E. A. Vidoto, O. R. Nascimento, C. A. P. Leite, O. A. Serra and Y. Iamamoto, “Synthesis of Fluorinated Metalloporphyrinosilica Imprinted with Templates through Sol-gel Process,” Jour- nal of Non-Crystalline Solids, Vol. 273, No. 1-3, 2000, pp. 100-108. doi:10.1016/S0022-3093(00)00149-6

has been cited by the following article:

• TITLE: Cationic Metalloporphyrins Imobilized in Faujasite Zeolites as a Cytochrome P-450 Mimic

  AUTHORS: Luciana P. B. Lôvo, Fabiana C. Skrobot, Gianluca C. Azzellini, Yassuko Iamamoto, Ieda L. V. Rosa

  KEYWORDS: Metalloporphyrin; Iodosylbenzene; Hydrocarbon Oxidation; Y Zeolite

  JOURNAL NAME: Modern Research in Catalysis, Vol.2 No.2, April 29, 2013

  ABSTRACT: Metalloporphyrins immobilized into NaY zeolite are described as catalysts for hydrocarbon oxyfuntionalization. Manganese(III) and iron(III)tetrakis(4-N-methylpyridyl)-porphyrin (MnP1 and FeP1), and manganese(III) and iron(III) tetrakis(4-N-benzylpiridil)-porphyrin (MnP2 and FeP2) were impregnated (MnP1-NaYimp, FeP1-NaYimp, MnP2-NaYimp, FeP2-NaYimp, respectively) and encapsulated (MnP1-NaY, FeP1-NaY, MnP2-NaY and FeP2-NaY) into the NaY zeolite. These catalysts were used in the oxidation of (Z)-cyclooctene, cyclohexane, and adamantane by iodosylbezene (PhIO). These systems were able to epoxidize (Z)-cyclooctene with cis-epoxycyclooctane yields as high as 100%. By using cyclohexane and adamantane as substrate, the susceptibility of the benzyl groups on the porphyrin ring of the MnP materials, led to a different distribution of the oxidized products. With FePs, this susceptibility was not detected because the species responsible for the oxidations, FeIV(O)P·+, is more active than MnV(O)P. In conclusion, cationic metalloporphyrins immobilized into NaX zeolites, are good cytochrome P-450 models is less polar solvents since the selectivity of the system indicates the “in cage” solvent oxygen rebound oxidative process.