Critical Parameters and Magnetocaloric Effect of the La5/8Ca3/8Mn0.9750Pd0.025O3 Compound
L. V. Bau, N. M. An
Hong Duc University, Thanh Hoa, Vietnam.
DOI: 10.4236/msa.2014.512086   PDF    HTML   XML   4,571 Downloads   5,372 Views   Citations

Abstract

The La5/8Ca3/8Mn0.9750Pd0.025O3 compound was studied using DC magnetization measurements. The data were analyzed in the paramagnetic-ferromagnetic phase transition region by the Arrott plot method. The results show the Curie temperature TC ~ 247.8 K and the critical exponents of b = 0.48633, g = 1.18623 and d = 3.431682. The values of the critical exponents are between the mean- field theory and 3D Ising model. The magnetocaloric value is ~5 J/kgK, extracted from the M(H) curves.

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Bau, L. and An, N. (2014) Critical Parameters and Magnetocaloric Effect of the La5/8Ca3/8Mn0.9750Pd0.025O3 Compound. Materials Sciences and Applications, 5, 857-862. doi: 10.4236/msa.2014.512086.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] De Teresa, J.M., Ibarra, M.R., Algarabel, P.A., Ritter, C., Marquina, C., Blasco, J., Garca, J., del Moral, A. and Arnold, Z. (1997) Evidence for Magnetic Polarons in the Magnetoresistive Perovskites. Nature (London), 386, 256-259.
http://dx.doi.org/10.1038/386256a0
[2] Uehara, M., Mori, S., Chen, C.H. and Cheong, S.-W. (1999) Percolative Phase Separation Underlies Colossal Magnetoresistance in Mixed-Valent Manganites. Nature (London), 399, 560-563.
[3] Kaul, S.N. (1985) Static Critical Phenomena in Ferromagnets with Quenched Disorder. Journal of Magnetism and Magnetic Materials, 53, 5-53.
http://dx.doi.org/10.1016/0304-8853(85)90128-3
[4] Martin, M.C., Shirane, G., Endoh, Y., Hirota, K., Moritomo, Y. and Tokura, Y. (1996) Near-Edge X-Ray-Absorption Study of Transition-Metal-Implanted YBa2Cu3O7-δ. Physical Review B, 53, 9412.
http://dx.doi.org/10.1103/PhysRevB.53.9412
[5] Freitas, R.S., Haetinger, C., Pureur, P., Alonso, J.A. and Ghivelder, L. (2001) Static Critical Behavior of the Ferromagnetic Transition in LaMnO3.14 Manganite. Journal of Magnetism and Magnetic Materials, 226-230, 569-571.
http://dx.doi.org/10.1016/S0304-8853(00)00683-1
[6] Shin, H.S., Lee, J.E., Nam, Y.S., Ju, H.L. and Park, C.W. (2001) First-Order-Like Magnetic Transition in Manganite Oxide La0.7Ca0.3MnO3. Solid State Communications, 118, 377-380.
http://dx.doi.org/10.1016/S0038-1098(01)00123-5
[7] Hong, C.S., Kim, W.S. and Hur, N.H. (2001) Transport and Magnetic Properties in the Ferromagnetic Regime of La1-xCaxMnO3. Physical Review B, 63, 092504.
http://dx.doi.org/10.1103/PhysRevB.63.092504
[8] Mira, J., Rivas, J., Rivadulla, F., Vazquez-Vazquez, C. and Lopez-Quintela, M.A. (1999) Change from Firstto Second-Order Magnetic Phase Transition in La2/3(Ca, Sr)1/3MnO3 Perovskites. Physical Review B, 60, 2998.
http://dx.doi.org/10.1103/PhysRevB.60.2998
[9] Anderson, P.W. and Hasegawa, H. (1955) Considerations on Double Exchange. Physical Review, 100, 675.
http://dx.doi.org/10.1103/PhysRev.100.675
[10] Bau, L.V., Van Khiem, N., Phuc, N.X., Van Hong, L. and Nam, D.N.H. (2009) Magnetoresistance and Magnetocaloric Properties of La0.7Sr0.3Co0.95Mn0.05O3 Compound. Journal of Physics: Conference Series, 187, Article ID: 012073.
[11] Chau, N., Niem, P.Q., Nhat, H.N., Luong, N.H. and Tho, N.D. (2003) Influence of Cu Substitution for Mn on the Structure, Magnetic, Magnetocaloric and Magnetoresistance Properties of La0.7Sr0.3MnO3 Perovskites. Physica B: Condensed Matter, 327, 214-217.
http://dx.doi.org/10.1016/S0921-4526(02)01731-3
[12] Gam, D.T.H., Hai, N.H., Van Vu, L., Luong, N.H. and Chau, N. (2009) The Existence of Large Magnetocaloric Effect at Low Field Variation and the Anti-Corrosion Ability of Fe-Rich Alloy with Cr Substituted for Fe. Journal of Physics: Conference Series, 187, Article ID: 012067.
[13] Duc, N.H., Thanh, T.D., Tam, L.T.T., Tuan, B.M., Thanh, P.T., Yen, N.H., Long, P.T. and Dan, N.H. (2010) Study on Synthesis, Structure and Magnetocaloric Properties of CoMn1-xFexSi Alloys. Presented at the 5th International Workshop on Advanced Materials Science and Nanotechnology, Ha Noi.
[14] Zhang, Y.D., Zhang, P., Kim, K., Yu, S.-C., Dan, N.H. and Hou, X.L. (2010) Magnetic Properties and Giant Magnetocaloric Effects on the NiMn0.9Sb0.1 Compound. Journal of the Korean Physical Society, 57, 1983-1986.
[15] Bau, L.V., Khiem, N.V., Phuc, N.X., Hong, L.V., Nam, D.N.H. and Nordblad, P. (2010) Observation of Mixed-Phase Behavior in the Mn-Doped Cobaltite La0.7Sr0.3Co1-xMnxO3 (x = 0-0.5). Journal of Magnetism and Magnetic Materials, 322, 753-755.
http://dx.doi.org/10.1016/j.jmmm.2009.10.054
[16] Kadano, L.P., Gotze, W., Hamblen, D., Hecht, R., Lewis, E.A.S., Palciauskas, V.V., Rayl, M., Swift, J., Aspnes, D. and Kane, J. (1967) Static Phenomena Near Critical Points: Theory and Experiment. Reviews of Modern Physics, 39, 395.
http://dx.doi.org/10.1103/RevModPhys.39.395
[17] Fisher, M.E., Ma, S.-K. and Nickel, B.G. (1972) Critical Exponents for Long-Range Interactions. Physical Review Letters, 29, 917.
http://dx.doi.org/10.1103/PhysRevLett.29.917

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