G. A. Bagirzade, V. Y. Sheinin, Z. Y. Magerramova and R. G. Rizaev, “Towards the Issue on Separation of Crystalline Mixture of the Main Products of Vapor Phase Ammoxidation of O-Xylene and Ist 4-Substitutives,” Azerbaijan Chemical Journal, Vol. 1, 2000, pp. 60-63.

has been cited by the following article:

• TITLE: Synthesis of 4-Phenylphthalonitrile by Vapor-Phase Catalytic Ammoxidation of Intermediate 4-Phenyl-o-Tolunitrile: Reaction Kinetics

  AUTHORS: G. A. Bagirzade, D. B. Tagiyev, M. R. Manafov

  KEYWORDS: Catalytic Ammoxidation; Partial Pressures; 4-Phenylphthalimide; Vapor-Phase; Electron-Donorship; Kinetic Measurements

  JOURNAL NAME: Modern Research in Catalysis, Vol.3 No.1, January 7, 2014

  ABSTRACT: Kinetic regularities of 4-phenyl-o-tolunitrile ammoxidation on V-Sb-Bi-Zr/γ-Al2O3 oxide catalyst in the temperature interval 633 - 673 K have been studied. It has been established that rates of conversion of 4-phenyl-o-tolu- nitrile into the aimed 4-phenylphthalonitrile and CO2 are described by half-order equation on concentration of substratum and to be independent of the oxygen and ammonia partial pressures. It has been revealed that formation of 4-phenylphthalimide from byproducts is due to hydrolysis of 4-phenylphthalonitrile; carbon dioxide is produced by oxidation of 4-phenyl-o-tolunitrile and decarboxylation of 4-phenylphthalimide, and 4-phenylben- zonitrile is produced from 4-phenyl-o-tolunitrile and 4-phenylphthalimide.