Conservation of Energy in Classical Mechanics and Its Lack from the Point of View of Quantum Theory ()

Stanisław Olszewski^{}

Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland.

**DOI: **10.4236/jmp.2016.716200
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Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland.

It is pointed out that the property of a constant energy characteristic for the circular motions of macroscopic bodies in classical mechanics does not hold when the quantum conditions for the motion are applied. This is so because any macroscopic body—lo-cated in a high-energy quantum state—is in practice forced to change this state to a state having a lower energy. The rate of the energy decrease is usually extremely small which makes its effect uneasy to detect in course of the observations, or experiments. The energy of the harmonic oscillator is thoroughly examined as an example. Here our point is that not only the energy, but also the oscillator amplitude which depends on energy, are changing with time. In result, no constant positions of the turning points of the oscillator can be specified; consequently the well-known variational procedure concerning the calculation of the action function and its properties cannot be applied.

Keywords

Classical Mechanics and Conservation of Energy, Motion Quantization of Macroscopic Bodies, Energy and Time of Transitions between Quantum States, Harmonic Oscillator Taken as an Example

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Olszewski, S. (2016) Conservation of Energy in Classical Mechanics and Its Lack from the Point of View of Quantum Theory. *Journal of Modern Physics*, **7**, 2316-2328. doi: 10.4236/jmp.2016.716200.

1. Introduction

Mechanics is usually considered as a fundamental part of physics because of its role in establishing the physical ideas. In fact, with its aid the motion kinds of the bodies were rather easily percepted and classified according to their character. A systematic study of mechanics was stimulated especially by astronomy. Here a fundamental guide became an access to a less or more accurate repetition of the observed effects and events.

In result, the best examined motions could be classified as belonging to two domains. One of them concerned the periodic motions where the body returns to its original position after some period of time, another domain of mechanics considered typical progressive motions in space and time. For this second kind of motions the top results could be obtained in the framework of the relativistic theory. The main feature in description of this kind of motions became a necessary coupling between the space intervals and intervals of time.

Evidently another characteristics than for progressive motions became dominant in describing the periodic motions. Here a principal mechanical parameter is the system energy. A constant property of that parameter was at the basis of the whole mechanics of the examined system. As far as the motion of a celestial body―especially that present in the solar system―was examined, the theoretical framework based on the conser- vation property of energy seemed to be fully satisfactory; see e.g. [1] [2] . A difficulty came when the atomic systems were discovered and―at the initial stage of the quantum theory―the periodic character of the electron motion in the atom was attempted to be described in a way not much different than applied for the body motion in the solar system. The main change which had to be taken into account concerned the fact that a single electron particle in the atom―concretely the hydrogen atom―could assume different but strictly specified energy values called the energy states. Excepting for the state having the lowest energy, an occupation of the other, i.e. higher energy levels, could be only temporary. This is so because at some time moment―undefined by the theory―the electron is going from a state of a higher energy to the state of a lower energy. The transition process is connected with the emission of energy equal to a difference between the initial and final levels of energy. The Bohr theory could―with a high accu- racy―to define the energy levels in the atom and corresponding differences between them [3] [4] . A difficulty―rather fundamental―was due to the fact that the time of the electron transition process between the states remained an unknown quantity.

In result the emission intensity of energy in the atom was specified solely with the aid of a complicated quantum-mechnical radiation theory based on a probabilistic back- ground [5] [6] . Complication of such calculations became evident because of necessity of the use of possibly accurate electron wave functions [4] [7] [8] . A difficulty of the access to such functions increased very rapidly with increase of the number of electron particles present and interacting in the atom.

Only recently the time interval of the electron transitions could be estimated with no reference to the wave functions. This was done with the aid of the classical electrody- namics in which the Joule-Lenz theory of the dissipated energy has been adapted to the quantum electron transitions [9] [10] [11] [12] [13] . For, when two neighbouring quantum levels separated by the energy interval

(1)

are considered, the time of the electron transition between the levels is given by the formula

(2)

where is the Planck constant

The formula (2) has occurred to be valid also for other quantum systems than the hydrogen atom [9] [12] . Here a rather fundamental question could be raised what is the relation between and when

(3)

and

(4)

so the interval in (3) concerns the non-neighbouring quantum levels. An approach to this problem is presented in Section 2.

In general, the classical mechanics and quantum theory are seldom compared, since usually they are applied to different―respectively macroscopic and microscopic―areas of physics. Perhaps a best known comparison is represented by the Ehrenfest theorem according to which the Hamilton equations are shown to be equally applicable to the classical particles and quantum wave-packets [7] . In the case of the present approach a comparison of the quantum and classical theory could be extended to such classical systems like planets and satellites, or the macroscopic harmonic oscillator.

Basing on the old quantum theory [14] it has been found for planets and satellites that their energy can by no means remain a constant number but should decrease systematically with time [15] , on condition the masses of the gravitationally interacting bodies remain unchanged. In the present paper the case of a classical harmonic oscil- lator is examined. In fact an approximate agreement of the both kinds―classical and quantum―approaches can be considered as satisfactory. This is so because the rate of the energy decrease of classical systems calculated with the aid of the quantum theory is exceedingly small.

The point considered in the present paper―as well as in [15] ―seems to be fully new and never examined before.

2. Energy Emission and Transition Times of Electrons between Non-Neighbouring Quantum Levels

In this case the formula (2) does not hold. In place of it one of the factors entering (2) becomes

(5)

on condition we take for the components in (5) the expressions:

(6)

Evidently any difference on the right of (6) concerns the neighbouring electron levels.

Time interval and energy interval enter (2) on an equal footing, therefore we assume that for we have

(7)

where the formulae for the components in (7) are referred to the energy components in (5) by:

(8)

The formulae (8) hold because the relations between the energy differences and time differences concerning the neighbouring electron levels are dictated by the formula (2).

The validity of transition intensities

(9)

calculated according to (5)-(8) (see [16] [17] ) was confirmed by comparing the ratios of the intensities calculated in (9) with the quantum-mechanical ratios of transition probabilities in the hydrogen atom; see [8] . In general the agreement of both kinds of approach―quantum-mechanical and the present one―can be considered as satisfac- tory. It should be noted that the next interval of time begins immediately after a former one, which is a situation similar to the behaviour of the energy intervals in the emission process, where a lower interval of energy begins immediately after a higher one.

In the next section (Section 3) the energy relations for a macroscopic harmonic oscillator are considered.

3. Energy Relations for a Macroscopic Harmonic Oscillator

Classically a well-known property of energy of the harmonic oscillator, which―for the sake of simplicity―can be reduced to a linear system, is its conservation with time [1] [18] . In course of the oscillator motion we have two different energy components corre- sponding to the kinetic and potential energy, respectively, which add together at any time to a constant number of the total energy dependent solely on the oscilllator ampli- tude and the oscillator constant:

(10)

is the oscillator mass, -the oscillator velocity, denotes the position of the oscillating particle.

The is coupled with the oscillator frequency by the relation

(11)

the frequency is dependent on the oscillation period:

(12)

As far as and remain constant numbers, no change of the total oscillator energy (10) can be obtained. By taking the boundary conditions of [1] we arrive at the formula

(13)

where is the time variable.

The quantization of the oscillator is a simple task. We have the velocity

(14)

the momentum

(15)

and the integral

(16)

If the integral (16) is extended over the time interval necessary to close the path of the body, we obtain the quantum condition [1]

(17)

where is a positive integer number; see also (12). The formula (17) gives

(18)

therefore

(18a)

Respectively the oscillator energies are [see (10) and (11)]:

(19)

(19a)

and their difference becomes

(20)

Evidently at and we have the turning points of the oscillator at which the kinetic energy vanishes in the classical case; see (10).

4. Upper Limit of the Oscillator Frequency Due to the Energy-Time Uncertainty Principle and an Upper Limit of the Emission Rate

There exists a limit of the time interval necessary for the electron transition pro- cess between two quantum levels. First this interval is coupled with the energy interval between the nearest quantum levels by the formula (2), but another coupling is given by the formula called the uncertainty principle of energy and time [11] [12] [19] [20] [21] :

(21)

This relation replaces an earlier formula coupling and given by Heisen- berg [7] [22]

(22)

In fact a substitution of the quantum formula (2) deduced from the Joule-Lenz law into (21) gives the relation

(23)

from which we obtain

(24)

The result on the right of (24) is similar to that obtained earlier also on the basis of the energy-time uncertainty principle [4] [12] [23] :

(25)

In calculating the emission process of a single electron transition we have the in- tensity

(26)

because (26) gives

(27)

which is evidently identical with the formula (2):

(28)

On the other side from (20) we obtain

(29)

In effect from (27) and (29) we arrive at the equality

(30)

which is a situation characteristic not only for the harmonic oscillator but also for other quantum systems [9] [11] [12] [24] . A substitution of (30) into (24) gives

(31)

therefore

(32)

This relation, which for the electron mass is equivalent to

(33)

represents the upper limit of the frequency of the electron oscillator.

A substitution of result (32) into (29) gives immediately an upper limit for the energy interval between the neighbouring quantum levels:

(34)

Respectively the value of the frequency limit in (34) is equal to

(34a)

A characteristic point is that the upper limit presented in (34a) is proportional to the particle mass as well as the square of the speed of light.

There exists also an upper limit of the emission rate of energy. It can be shown that this limit remains the same independently of that whether it is derived on the basis of the formula (2), or directly from the Joule-Lenz law for the dissipation of energy. In the case when the formula (2), or (26), is applied we have from (24) and (34):

(35)

On the other hand, the emission rate obtained from the Joule-Lenz law is

(36)

where is the electric resistance of the current due to the one-electron transport:

(37)

is the electron charge and is the time period in (30) equal to the time interval of the electron transition. For in quantum systems we obtain a constant number [9] [12]

(38)

(characteristic for the integer quantum Hall effect [25] ), so

(39)

because of the formula (24).

Evidently the results based on the quantum uncertainty principle are of not much use for the macroscopic level.

5. Dissipation of Energy of the Macroscopic and Microscopic Oscillator

Our aim is to show that the dissipation of energy concerns equally a microscopic and macroscopic oscillator, though evidently it is relatively much less important in the macroscopic case.

In the microscopic situation we have a well-known emission of the quanta given in (29). On the other hand, for the macroscopic case it was believed that no emis- sion can take place, so the oscillations are going on without any loss of energy. In fact by applying the quantum formalism it is easy to show that this energy conservation does not hold.

Let us assume a macroscopic oscillator having mass g, the amplitude length cm and the time period of the oscillations is

(40)

This implies the quantum condition [see (17)]

(41)

therefore

(42)

Equation (42) indicates that a very high quantum state is occupied by the oscillator, however this state can be lowered.

Since the energy of the oscillator in state is

(43)

a lowering of (43) by the amount

(44)

leads to the energy

(45)

In the quantum approach to the Joule-Lenz law [9] [12] the lowering of energy represented by (44) takes place within the time interval equal to the oscillation period, i.e.

(46)

So―because of (40) and inferences before it―the formula (44) corresponds to the amount of emitted energy:

(44a)

This is a very small amount of energy if we compare it with the energy of state in (43) which is

(47)

Practically a full loss of the energy (47) will occur when the oscillator being in state will perform a transfer to the lowest quantum state. This can take place within the time

(48)

if we note that approximately

(49)

Therefore―strictly speaking―the energy of the oscillator cannot be conserved. How- ever, the rate of decrease of energy is extremely small which makes uneasy to detect it in course of the observations or experiments.

6. Discussion: Energy Decrease and the Damping Term of the Oscillator

The decrease of the oscillator energy can be examined with the aid of the corresponding damping coefficient [26] . It is given by the equation

(50)

Here is the kinetic energy of the oscillator and―the average value of. It is easy to show that

(51)

where is the total energy of the oscillator given in (10). For the kinetic part we have from (14)

(52)

because of (11), and the same result gives the averaged potential energy.

Since

(53)

we find that

(54)

or

(55)

For the classical macroscopic oscillator considered in Sec. 5 we obtain from (40) and (42)

(55a)

A characteristic point is that a similar value for can apply to a quantum system of electrons oscillating along the Fermi surface of a metal upon the action of an external magnetic field. In this case the formula (55) for takes the form:

(56)

where is the electron mass, is assumed to approach the Fermi energy of a metal and is the electron circulation frequency due to the magnetic field; see e.g. [27] . Since

(57)

(58)

and

(59)

we arrive at:

(60)

This becomes not different from that obtained in the macroscopic case [see (55a)] on condition the equality between (55a) and (60) is satisfied:

(61)

so

(62)

The size of the frequency obtained in (62) is rather often applied in experiments examining the Fermi surface and magnetoresistance of metals with the aid of the magnetic field [27] .

7. Conclusions

In some earlier papers by the author [9] [10] [12] , an attempt has been done to establish the time interval necessary for the electron transitions between states and; these states were classified to be periodic in time. By assuming that the energy interval between the states is a positive quantity [see (1)], the transition re- presents an emission process of energy. A reconstruction of the classical Joule-Lenz law for the dissipation of energy suitable to the treatment of the quantum transitions gives― in the first step―the result that is coupled with by the formula (2) or (28).

Another property of entering (2) or (28) became the equation

(63)

[see also (30)], where is the time period characteristic for the quantum state [9] [11] [12] [24] . In practice―when in (1), or a similar difference of energy

(64)

between states and, are small―the time period is not much different than or.

The idea of the former [15] and present paper was to consider the classical mecha- nical systems of a periodic character on a quantum footing in spite of their macroscopic size. This has been done on the basis of the old quantum theory. In course of the treat- ment it became of importance to know―in the first step―whether or―are small, in the next step―whether the formula (2) together with (63) can be satisfied also in the macroscopic case.

In [15] the celestial bodies of the solar system have been examined. With the neglected luminosity effect represented by the mass decrease of the Sun due to its light emission, the validity of (2) has been checked, first, by calculating with the aid of the orbit parameters, next by taking into account the formula (63). The data for the Earth planet considered as an example were applied in the numerical calculations.

The present paper concerns the quantum approach to the macroscopic harmonic oscillator. In this treatment the validity of (2) and (63) could be easily confirmed. In any quantum calculation done on the macroscopic body the number became very high indicating an existence of small between the neighbouring quantum states.

A basic result obtained from the quantum approach to the periodic macroscopic systems is that―strictly speaking―no conservation of energy does exist for such sys- tems, as far as the system does not reach its ground state represented by the lowest possible energy. In reality any of the examined systems had a huge index of its quantum state, but these states can be gradually left by the body in a way similar to the spontaneous emission of light known for the small quantum systems. A difference between the macroscopic and microscopic bodies is quantitative, not a qualitative one: the speed of emission by a macroscopic body, like the Earth or macroscopic oscillator, is exceedingly small. In effect, since the actual quantum number of the body is high, a transition to the lowest body state at becomes an extremely long process in time.

This result can be compared with a totally different situation of the micoscopic systems like atoms. Here the energy emitted in a single transition is large, when com- pared with the total energy possessed by the electron, and the number of steps necessary to attain the ground state is relatively small. This makes the emission rate of energy relatively large.

There remains still the problem of causality of the transition process between the quantum states. In fact the very existence of these states is rather postulated by the (old) quantum theory than derived from a more advanced formalism, for example quantum mechanics. But there is no reason to reject such postulate.

Another problem is the time of the body transitions between the quantum states. This point seems to be carefully avoided by many of quantum physicists instead to be put into a calculational practice. In fact any transition rate of energy is considered from the very beginning of quantum theory―also the old one―solely on a probabilistic footing [5] [6] . This kind of approach does not apply to the theory outlined in the present paper: here, in course of any period of time characteristic for the body motion, the body energy can be decreased by a very small amount equal to the Planck constant divided by. The interval can be derived also on the basis of classical electrodynamics [13] which implies its deterministic and not probabilistic character. In effect the transitions between the quantum energy levels discussed in the paper, which make the periodic motion equal to an irreversible process, should be considered rather as a compulsory result and not solely like less or more probable phenomenon.

Conflicts of Interest

The authors declare no conflicts of interest.

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