Effects of Polysilane-Coating on Interface of Electrofusion Joints for Maintaining Strength

Abstract

The fusion strength of electrofusion joints using the polyethylene (PE) pipe connection greatly depends on the amount of sand which adheres to the interface by wind and so on, because there is no flow of melted resin at the fusion interface on electrofusion joints. Therefore, it is necessary to develop a method to prevent the fusion strength from reducing even in the case of sand adhesion. In this study, the fusion interface coated with polysilane, a kind of silicon polymer, effectively prevented the reduction of the fusion strength even if contaminated by sand. It was found that it brought the improvement of the fusion strength since when there was polysilane on the fusion interface. PS deeply permeated the polyethylene layer and lowered the viscosity of polyethylene.

Share and Cite:

Murase, H. , Kawasaki, S. , Kitaoka, T. , Furukawa, J. , Ueda, H. , Nishimura, H. and Yamada, K. (2015) Effects of Polysilane-Coating on Interface of Electrofusion Joints for Maintaining Strength. Materials Sciences and Applications, 6, 322-331. doi: 10.4236/msa.2015.64037.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] Nishimura, H., Suyama, M., Inoue, F., Higuchi, Y. and Ishikawa, T. (1995) An Evaluation Method for Electrofusion Joint Strength of Polyethylene Pipes for Gas Distribution. Proceedings of Plastics Pipes IX, 162-167.
[2] Marshall, G.P., Hepburn, D.S. and Netherwood, N. (1995) Improvements in Electrofusion Welding in the US Water Industry. Proceedings of Plastics Pipes IX, 153-161.
[3] Nishimura, H., Suyama, M., Inoue, F. and Ishikawa, T. (1995) Design and Evaluation Methods for Electrofusion Joints of Polyethylene Pipes for Gas Distribution. Proceedings of ANTEC 1995, 1212-1216.
[4] Tubakimoto, T., Nishimura, H., Ishikawa, T. and Ueda, H. (1997) Trend in Technological Development of Polyethylene Pipes. International Plastic Pipe Symposium, 177-184.
[5] Yajima, S., Hayashi, J. and Omori, M. (1975) Continuous Silicon Carbide Fiber of High Tensile Strength. Chemistry Letters, 4, 931-934.
http://dx.doi.org/10.1246/cl.1975.931
[6] Hasegawa, Y. and Okamura, K. (1986) Synthesis of Continuous Silicon Carbide Fibre. Part 4. The Structure of Polycarbosilane as the Precursor. Journal of Materials Science, 21, 321-328. http://dx.doi.org/10.1007/BF01144739
[7] Srinivasan, R. (1986) Ablation of Polymers and Biological Tissue by Ultraviolet Lasers. Science, 234, 559-565.
http://dx.doi.org/10.1126/science.3764428
[8] Miller, R.D., Willson, C.G., Wallraff, G.M., Clecak, N., Sooriyakumaran, R., Michl, J., Karatsu, T., McKinley, A.J., Klingensmith, K.A. and Downing, J. (1989) Polysilanes: Photochemistry and Deep UV Lithography. Polymer Engineering Science, 29, 882-886.
http://dx.doi.org/10.1002/pen.760291311
[9] Miller, R.D., Wallraff, G.M., Clecak, N., Sooriyakumaran, R., Michl, J., Karatsu, T., McKinley, A.J., Klingensmith, K.A. and Downing, J. (1989) Polysilanes: Solution Photochemistry and Deep UV Lithography. Polymer Materials Science Engineering, 60, 49.
http://dx.doi.org/10.1021/bk-1989-0412.ch008
[10] Miller, R.D. and Michl, J. (1989) Polysilane High Polymers. Chemical Reviews, 89, 1359-1410.
http://dx.doi.org/10.1021/cr00096a006
[11] Miller, R.D. (1989) Polysilanes—A New Look at Some Old Materials. Angewandte Chemie International Edition in English, 28, 1733-1740.
http://dx.doi.org/10.1002/anie.198917331
[12] West, R., David, L.D., Djurovich, P.I., Stearley, K.L., Srinivasan, K.S.V. and Yu, H. (1981) Phenylmethylpolysilanes: Formable Silane Copolymers with Potential Semiconducting Properties. Journal of the American Chemical Society, 103, 7352-7354.
http://dx.doi.org/10.1021/ja00414a061
[13] Naarman, H., Theophilou, N., Geral, L., Sledz, J. and Schien, F. (1988) Electrically Conductive Polysilanes. German Patent DE3634281.
[14] Kepler, R.G., Zeigler, J.M., Harrah, L.A. and Kurtz, S.R. (1987) Photocarrier Generation and Transport in σ-Bonded Polysilanes. Physical Review B, 35, 2818-2822.
http://dx.doi.org/10.1103/PhysRevB.35.2818
[15] Fujino, M. (1987) Photoconductivity in Organopolysilanes. Chemical Physics Letters, 136, 451-453.
http://dx.doi.org/10.1016/0009-2614(87)80285-3
[16] Marinero, E.E. (1985) Laser Multiphoton Processes in Thin Films: Non-Linear Photochemistry of Organosilane Polymers. Chemical Physics Letters, 115, 501-506.
http://dx.doi.org/10.1016/0009-2614(85)85179-4
[17] Kajzar, F., Messier, J. and Rosilio, C. (1986) Nonlinear Optical Properties of Thin Films of Polysilane. Journal of Applied Physics, 60, 3040-3044.
http://dx.doi.org/10.1063/1.337759
[18] Baumert, J.C., Bjorklund, G.C., Jundt, D.H., Jurich, M.C., Looser, H., Miller, R.D., Rabolt, J., Soorijakumaran, R., Swalen, J.D. and Twig, R.J. (1988) Temperature Dependence of the Third-Order Nonlinear Optical Susceptibilities in Polysilanes and Polygermanes. Applied Physics Letters, 53, 1147-1149.
http://dx.doi.org/10.1063/1.100040
[19] Murase, H., Sakamoto, H. and Fujiki, T. (2008) Manufacturing Method of Polysilane Copolymers. Patent JP 4205354.
[20] Murase, H., Fujiki, T. and Sakamoto, H. (2000) Synthesis of Polysilanes and Related Polymers Using Magnesium and Metal Chloride Catalysts. RadTech Japan Symposium, 110.
[21] Murase, H., Sakamoto, H. and Fujiki, T. (2010) Manufacturing Method of Polysilane Using Activated Magnesium. Patent JP 4559642.
[22] Kashimura, S., Tane, Y., Ishifune, M., Murai, Y., Hashimoto, S., Murase, H., et al. (2008) Practical Method for the Synthesis of Polysilanes Using Mg and Lewis Acid System. Tetrahedron Letters, 49, 269-271.
http://dx.doi.org/10.1016/j.tetlet.2007.11.088
[23] Schaefer, J., Stejekal, E.O. and Buchdahl, R. (1977) Magic-Angle 13C NMR Analysis of Motion in Solid Glassy Polymers. Macromolecules, 10, 384-405.
http://dx.doi.org/10.1021/ma60056a031
[24] Earl, W.L. and Vander Hart, D.L. (1979) Observations in Solid Polyethylenes by Carbon-13 Nuclear Magnetic Resonance with Magic Angle Sample Spinning. Macromolecules, 12, 762-767. http://dx.doi.org/10.1021/ma60070a045

Copyright © 2023 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.