Determination of the Stabilization Time of the Solution-Air Interface for Aggregates Formed by NaC in Mixtures with SDS and PEO, Investigated by Dynamic Surface Tension Measurements

DOI: 10.4236/soft.2014.31001   PDF   HTML     4,268 Downloads   7,533 Views   Citations

Abstract

The properties of mixtures of poly (ethylene oxide) (PEO) and mixed micelles formed from sodium cholate (NaC) and sodium dodecyl sulfate (SDS) in tris/HCl buffered solutions at pH 9.00 were investigated by measuring the mean surface tension. The variation in the superficial tension as a function of the time after formation of solutions containing PEO and NaC was characterized by monitoring the time required for the system to reach equilibrium between the micellar and aqueous phases. These results could serve as a reference for the minimum aging time required for solutions before any surface tension measurements can be performed.

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Raupp, G. , C. Felippe, A. , Allievi Frizon, T. , da Silva, L. , da Silva Paula, M. and G. Dal-Bó, A. (2014) Determination of the Stabilization Time of the Solution-Air Interface for Aggregates Formed by NaC in Mixtures with SDS and PEO, Investigated by Dynamic Surface Tension Measurements. Soft, 3, 1-10. doi: 10.4236/soft.2014.31001.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] Taylor, D.J.F., Thomas, R.K. and Penfold, J. (2007) Polymer/Surfactant Interactions at the Air/Water Interface. Ad- vances in Colloid and Interface Science, 132, 69-110. http://dx.doi.org/10.1016/j.cis.2007.01.002
[2] Claesson, P.M., Makuska, R., Varga, I., Meszaros, R., Titmuss, S., Linse, P., Pedersen, J.S. and Stubenrauch, C. (2010) Bottle-Brush Polymers: Adsorption at Surfaces and Interactions with Surfactants. Advances in Colloid and Interface Science, 155, 50-57. http://dx.doi.org/10.1016/j.cis.2010.01.004
[3] Zanette, D., Ruzza, A.A., Froehner, S.J. and Minatti, E. (1996) Polymer-Surfactant Interactions Demonstrated by a Kinetic Probe: Degree of Ionization. Colloids and Surfaces, 108, 91-100. http://dx.doi.org/10.1016/0927-7757(95)03355-6
[4] Zanette, D., Froehner, S.J., Minatti, E. and Ruzza, A.A. (1997) Effects of Polymer and Salt Concentrations on Ketal Acid Hydrolysis in Solutions of Sodium Dodecyl Sulfate and Poly(Vinyl Pyrrolidone) or Poly(Ethylene Oxide). Langmuir, 13, 659-665. http://dx.doi.org/10.1021/la960557l
[5] Dal Bo, A., Schweitzer, B., Felippe, A.C., Zanette, D. and Lindman, B. (2005) Ethyl(Hydroxyethyl)Cellulose-Sodium Dodecanoate Interaction Investigated by Surface Tension and Electrical Conductivity Techniques. Colloid Surface A, 256, 171-180.
[6] Minatti, E. and Zanette, D. (1996) Salt Effects on the Interaction of Poly(Ethylene Oxide) and Sodium Dodecyl Sulfate Measured by Conductivity. Colloid Surface A, 113, 237-246. http://dx.doi.org/10.1016/0927-7757(96)03573-X
[7] Dal-Bó, A.G., Laus, R., Felippe, A.C., Zanette, D. and Minatti, E. (2011) Association of Anionic Surfactant Mixed Micelles with Hydrophobically Modified Ethyl(Hydroxyethyl)Cellulose. Colloid Surface A, 380, 100-106. http://dx.doi.org/10.1016/j.colsurfa.2011.02.028
[8] Dal-Bó, A.G. and Minatti, R.L.e.E. (2011) Autoassocia??o de misturas dos Surfactantes Dodecanoato de Sódio (SDoD) e Decanoato de Sódio (SDeC) com o Polímero Hidrofobicamente Modificado Etil(Hidroxietil)Celulose (EHEC). Química Nova, 34, 1001-1006. http://dx.doi.org/10.1590/S0100-40422011000600017
[9] Goddard, E.D. and Ananthapadmanabhan, K.P. (1993) Protein-Surfactant Interactions. In: Goddard, E.D. and Anan- thapadmanabhan, K.P., Eds., Interactions of Surfactants with Polymers and Proteins, CRC Press, Boca Raton, 319- 365.
[10] Holmberg, K., Jonsson, B., Holmberg, K. and Lindman, B. (2002) Surfactants and Polymers in Aqueous Solution. John Wiley & Sons, New York. http://dx.doi.org/10.1002/0470856424
[11] Gouin, S. and Zhu, X.X. (1998) Fluorescence and NMR Studies of the Effect of a Bile Acid Dimer on the Micellization of Bile Salts. Langmuir, 14, 4025-4029. http://dx.doi.org/10.1021/la971155w
[12] Hildebrand, A., Neubert, R., Garidel, P. and Blume, A. (2002) Bile Salt Induced Solubilization of Synthetic Phospha- tidylcholine Vesicles Studied by Isothermal Titration Calorimetry. Langmuir, 18, 2836-2847. http://dx.doi.org/10.1021/la011421c
[13] Felippe, A.C., Schweitzer, B., Dal Bo, A.G., Eising, R., Minatti, E. and Zanette, D. (2007) Self-Association of Sodium Cholate with Poly(Ethylene Oxide) Cooperatively Induced by Sodium Dodecyl Sulfate. Colloid Surface A, 294, 247-253. http://dx.doi.org/10.1016/j.colsurfa.2006.08.019
[14] Jiang, L., Wang, K., Deng, M., Wang, Y. and Huang, J. (2008) Bile Salt-Induced Vesicle-to-Micelle Transition in Catanionic Surfactant Systems: Steric and Electrostatic Interactions. Langmuir, 24, 4600-4606. http://dx.doi.org/10.1021/la7035554
[15] Eising, R., Felippe, A.C. and Domingos, J.B. (2011) Physicochemical Investigation of the Association of the Biosur- factants Sodium Cholate and Sodium Dodecanoate with Poly(ethyleneoxide). Journal of Dispersion Science and Technology, 33, 75-82. http://dx.doi.org/10.1080/01932691.2010.530094
[16] Fernandez-Leyes, M.D., Messina, P.V. and Schulz, P.C. (2011) Bile Salt Structural Effect on the Thermodynamic Properties of a Catanionic Mixed Adsorbed Monolayer. Colloid and Polymer Science, 289, 179-191. http://dx.doi.org/10.1007/s00396-010-2336-1
[17] Small, D.M., Penkett, S.A. and Chapman, D. (1969) Studies on Simple and Mixed Bile Salt Micelles by Nuclear Magnetic Resonance Spectroscopy. Biochimica et Biophysica Acta, 176, 178-189. http://dx.doi.org/10.1016/0005-2760(69)90086-1
[18] D’Alagni, M., D’Archivio, A.A., Galantini, L. and Giglio, E. (1997) Structural Study of the Micellar Aggregates of Sodium Chenodeoxycholate and Sodium Deoxycholate. Langmuir, 13, 5811-5815. http://dx.doi.org/10.1021/la970337n
[19] Djavanbakht, A., Kale, K.M. and Zana, R. (1977) Ultrasonic Absorption and Density Studies of the Aggregation in Aqueous Solutions of Bile Acid Salts. Journal of Colloid and Interface Science, 59, 139-148. http://dx.doi.org/10.1016/0021-9797(77)90348-4
[20] Dey, T. and Das, A.R. (2012) Physicochemical Study of Bile Salt-Polymer Micellar Aggregates. Zeitschrift für Physi-kalische Chemie, 226, 315-326. http://dx.doi.org/10.1524/zpch.2012.0172
[21] Oakenfull, D.G. and Fisher, L.R. (1977) The Role of Hydrogen Bonding in the Formation of Bile Salt Micelles. The Journal of Physical Chemistry, 81, 1838-1841. http://dx.doi.org/10.1021/j100445a031
[22] Kratohvil, J.P., Hsu, W.P. and Kwok, D.I. (1986) How Large Are the Micelles of Di-Alpha-Hydroxy Bile-Salts at the Critical Micellization Concentrations in Aqueous-Electrolyte Solutions—Results for Sodium Taurodeoxycholate and Sodium Deoxycholate. Langmuir, 2, 256-258. http://dx.doi.org/10.1021/la00068a026
[23] Jones, M.N. (1967) The Interaction of Sodium Dodecyl Sulfate with Polyethylene Oxide. Journal of Colloid and Interface Science, 23, 36-42. http://dx.doi.org/10.1016/0021-9797(67)90082-3
[24] Zanette, D., Felippe, A.C., Schweitzer, B., Dal Bo, A. and Lopes, A. (2006) The Absence of Cooperative Binding in Mixtures of Sodium Cholate and Poly(Ethylene Oxide) as Indicated by Surface Tension, Steady-State Fluorescence and Electrical Conductivity Measurements. Colloid Surface A, 279, 87-95. http://dx.doi.org/10.1016/j.colsurfa.2005.12.045
[25] Nahringbauer, I. (1997) Polymer-Surfactant Interaction as Revealed by the Time Dependence of Surface Tension. The EHEC/SDS/Water System. Langmuir, 13, 2242-2249. http://dx.doi.org/10.1021/la960976i
[26] Um, S.U., Poptoshev, E. and Pugh, R.J. (1997) Aqueous Solutions of Ethyl (Hydroxyethyl) Cellulose and Hydrophobic Modified Ethyl (Hydroxyethyl) Cellulose Polymer: Dynamic Surface Tension Measurements. Journal of Colloid and Interface Science, 193, 41-49. http://dx.doi.org/10.1006/jcis.1997.4990
[27] Stubenrauch, C., Albouy, P.A., von Klitzing, R. and Langevin, D. (2000) Polymer/Surfactant Complexes at the Water/Air Interface: A Surface Tension and X-Ray Reflectivity Study. Langmuir, 16, 3206-3213. http://dx.doi.org/10.1021/la991277j
[28] Djuve, J., Pugh, R.J. and Sjoblom, J. (2001) Foaming and Dynamic Surface Tension of Aqueous Polymer/Surfactants Solutions 1: Ethyl(Hydroxyethyl) Cellulose and Sodium Dodecyl Sulphate. Colloid Surface A, 186, 189-202. http://dx.doi.org/10.1016/S0927-7757(00)00787-1
[29] Nahringbauer, I. (1995) Dynamic Surface Tension of Aqueous Polymer Solutions, I: Ethyl(Hydroxyethyl)Cellulose (BERMOCOLL cst-103). Journal of Colloid and Interface Science, 176, 318-328. http://dx.doi.org/10.1006/jcis.1995.9961
[30] Zana, R. and Guveli, D. (1985) Fluorescence Probing Study of the Association of Bile Salt in Aqueous Solutions. The Journal of Physical Chemistry, 89, 1687-1690. http://dx.doi.org/10.1021/j100255a028
[31] Minatti, E., Norwood, D.P. and Reed, W.F. (1998) Surfactant/Polymer Assemblies. 2. Polyelectrolyte Properties. Macromolecules, 31, 2966-2971. http://dx.doi.org/10.1021/ma971319f
[32] Sugioka, H. and Moroi, Y. (1998) Micelle Formation of Sodium Cholate and Solubilization into the Micelle. Biochi- mica et Biophysica Acta (BBA)—Lipids and Lipid Metabolism, 1394, 99-110. http://dx.doi.org/10.1016/S0005-2760(98)00090-3

  
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