Synthesis, crystal structure, and catalytic properties of 2,2’-bipyridyl-dicyano-palladium(II)


In the solvothermal condition, a Pd(II) complex with a in situ synthesis ligand, [Pd(2,2’-bipy)2(CN)2] (1) was obtained and characterized by elemental analysis, IR, UV, TG, and powder X-ray analysis. The single crystal X-ray analysis showed that the title complex is different from the reported 2,2’-bipyridyl-dicyanopalladium(II) (2) in crystal system and structural parameters. The catalytic investigation for the reactions of the disproportionation of hydrogen peroxide and oxidation of sulfide showed that the complex 1 is an active homogeneous catalyst in the presence of imidazole and 2-sulfobenzoic acid, respectively.

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Tang, X. and Zhu, L. (2013) Synthesis, crystal structure, and catalytic properties of 2,2’-bipyridyl-dicyano-palladium(II). Open Journal of Inorganic Chemistry, 3, 71-75. doi: 10.4236/ojic.2013.34010.

Conflicts of Interest

The authors declare no conflicts of interest.


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