Share This Article:

Synthesis, crystal structure, and catalytic properties of 2,2’-bipyridyl-dicyano-palladium(II)

Abstract Full-Text HTML Download Download as PDF (Size:602KB) PP. 71-75
DOI: 10.4236/ojic.2013.34010    4,250 Downloads   8,206 Views   Citations

ABSTRACT

In the solvothermal condition, a Pd(II) complex with a in situ synthesis ligand, [Pd(2,2’-bipy)2(CN)2] (1) was obtained and characterized by elemental analysis, IR, UV, TG, and powder X-ray analysis. The single crystal X-ray analysis showed that the title complex is different from the reported 2,2’-bipyridyl-dicyanopalladium(II) (2) in crystal system and structural parameters. The catalytic investigation for the reactions of the disproportionation of hydrogen peroxide and oxidation of sulfide showed that the complex 1 is an active homogeneous catalyst in the presence of imidazole and 2-sulfobenzoic acid, respectively.

Conflicts of Interest

The authors declare no conflicts of interest.

Cite this paper

Tang, X. and Zhu, L. (2013) Synthesis, crystal structure, and catalytic properties of 2,2’-bipyridyl-dicyano-palladium(II). Open Journal of Inorganic Chemistry, 3, 71-75. doi: 10.4236/ojic.2013.34010.

References

[1] Chen, X.M. and Tong, M.L. (2007) Solvothermal in situ metal/ligand reactions: a new bridge between coordination chemistry and organic synthetic chemistry. Accounts of Chemical Research, 40, 162-170.
http://dx.doi.org/10.1021/ar068084p
[2] Zhang, X.M. (2005) Hydro(solvo)thermal in situ ligand syntheses. Coordination Chemistry Reviews, 249, 1201-1219. http://dx.doi.org/10.1016/j.ccr.2005.01.004
[3] Zhu, Y.L., Qu, L.L., Zhang, J., Ge, G.W., Li, Y.Z., Du, H.B. and You, X.Z. (2011) In situ formation of an unprecedented 3D microporous CuCN coordination polymer based on a semirigid tetrahedral linker. Inorganic Chemistry Communications, 14, 1644-1647.
[4] Sheldrick, G.M. (1997) SADABS, Program for bruker area detector absorption correction. University of Göttingen, Göttingen.
[5] Sheldrick, G.M. (1997) SHELXL-97, program for crystal structure refinement. University of G?ttingen, G?ttingen.
[6] Farrugia, L.J. (1999) WinGX suite for small-molecule single-crystal crystallography. Journal of Applied Crystallography, 32, 837-838.
http://dx.doi.org/10.1107/S0021889899006020
[7] Macrae, C.F., Edgington, P.R., McCabe, P., Pidcock, E., Shields, G.P., Taylor, R., Towler, M. and van de Streek, J. (2006) Mercury: Visualization and analysis of crystal structures. Journal of Applied Crystallography, 39, 453-457. http://dx.doi.org/10.1107/S002188980600731X
[8] Che, C.C., He, L.Y., Poon, C.K. and Mak, T.C.W. (1989) Solid-state emission of dicyanoplatium(II) and palladium(II) complexes of substituted 2,2’-bipyridines and isomorphous M(bpy)(CN)2 (bpy=2,2’-bipyridine, M=Pt, Pd). Inorganic Chemistry, 28, 3081-3083.
[9] Yang, X.J., Janiak, C., Heinze, J., Drepper, F., Mayer, P., Piotrowski, H. and Klufers, P. (2001) Heteroleptic 5,5’- disubstituted-2,2’-bipyridine complexes of ruthenium(II): spectral, electrochemical, and structural investigations. Inorganica Chimica Acta, 318, 103-116.
http://dx.doi.org/10.1016/S0020-1693(01)00414-5
[10] Miao, X.H. and Zhu, L.G. (2010) Supramolecular assembly under the control of the chelating ligand for the MnII/bridging ligands/3-sulfobenzoate system and catalytic properties for the disproportionation of hydrogen peroxide. New Journal of Chemistry, 34, 2403-2414.
http://dx.doi.org/10.1039/b9nj00428a
[11] Dubois, L., Caspar, R., Jacquamet, L., Petit, P. E., Charlot, M.F., Baffert, C., Collomb, M.N., Deronzier, A. and Latour, J.M. (2003) Binuclear manganese compounds of potential biological significance. Part 2. Mechanistic study of hydrogen peroxide disproportionation by dimanganese complexes: the two oxygen atoms of the peroxide end up in a dioxo intermediate. Inorganic Chemistry, 42, 4817-4827. http://dx.doi.org/10.1021/ic020646n
[12] Villalobos, L., Cao, Z., Fanwick, P.E. And Ren, T. (2012) Diruthenium(II,III) tetramidates as a new class of oxygenation catalysts. Dalton Transactions, 41, 644-650.
http://dx.doi.org/10.1039/c1dt11530h
[13] Barker, J.E. and Ren, T. (2008) Diruthenium(II,III) bis(tetramethyl-1,3-benzenedipropionate) as a novel catalyst for tert-butyl hydroperoxide oxygenation. Inorganic Chemistry, 47, 2264-2266.
[14] Devereux, M., McCann, M., Leon, V., McKee, V. and Ball, R.J. (2002) Synthesis and catalytic activity of manganese(II) complexes of heterocyclic carboxylic acids: X-ray crystal structures of [Mn(pyr)2]n, [Mn(dipic)(bipy)2]?/ 4.5H2O and [Mn(chedam)(bipy)]?/H2O(pyr=/2-pyrazinecarboxylic acid; dipic =/pyridine-2,6-dicarboxylic acid; chedam_/chelidamic acid (4-hydroxypyridine-2,6-dicarboxylic acid); bipy =/2,2-bipyridine). Polyhedron, 21, 1063-1071. http://dx.doi.org/10.1016/S0277-5387(02)00842-2?
[15] Viossat, V., Lemoine, P., Dayan, E., Dung, N.H. and Viossat, B. (2003) Synthesis, crystal structure and IR spectroscopy of MnII(2-IC)2(NC)(DMSO) and [MnII(2-IC)2 (phen)(H2O)]?DMA; (2-HIC, indole-2-carboxylic acid; phen, 1,10-phenanthroline; NC, 2,9-dimethyl-1,10-phenanthroline; DMSO, dimethyl sulfoxide; DMA, dimethyl acetamide); catalysts for the disproportionation of hydrogen. Polyhedron, 22, 1461-1470.
http://dx.doi.org/10.1016/S0277-5387(03)00126-8
[16] Hu W.T. and Zhu, L.G. (2013) Study on the synthesis, crystal structure and catalytic activity for thioanisol of a ruthenium complex with 3-sulfobenzoate and 2,2’-bipyridine ligands. Chinese Journal of Inorganic Chemistry, 29, 1109-1114.

  
comments powered by Disqus

Copyright © 2019 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.