Electrochemical Polymerization of 4,4-Dimethyl-2,2’-Bithiophene in Concentrated Polymer Liquid Crystal Solution - Journal of Materials Science and Chemical Engineering

MSCE > Vol.5 No.2, February 2017

Journal of Materials Science and Chemical Engineering

Volume 5, Issue 2 (February 2017)

ISSN Print: 2327-6045 ISSN Online: 2327-6053

Google-based Impact Factor: 1.21 Citations

Electrochemical Polymerization of 4,4-Dimethyl-2,2’-Bithiophene in Concentrated Polymer Liquid Crystal Solution ()

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Download as PDF (Size: 896KB) PP. 64-70

DOI: 10.4236/msce.2017.52007 1,893 Downloads 3,221 Views Citations

Author(s)

Naoto Eguchi, Kohsuke Kawabata, Hiromasa Goto^*

Affiliation(s)

Faculty of Pure and Applied Sciences, Division of Materials Science, University of Tsukuba, Tsukuba, Japan.

ABSTRACT

Electrochemical polymerization of 4,4’-dimethyl-2,2’-bithiophene (4DMBT) was carried out in a concentrated solution of hydroxypropyl cellulose (HPC) liquid crystal in N,N-dimethylformamide. Infrared absorption spectra suggested that the resultant polymer film contains HPC. This study demonstrates an electrochemical preparation of a polymer composite having liquid crystal order. We proposed a helical stacking composite model.

KEYWORDS

Conjugated Polymer, Electrochemical Polymerization, Polymer Liquid Crystal, Hydroxypropyl Cellulose

Share and Cite:

Eguchi, N. , Kawabata, K. and Goto, H. (2017) Electrochemical Polymerization of 4,4-Dimethyl-2,2’-Bithiophene in Concentrated Polymer Liquid Crystal Solution. Journal of Materials Science and Chemical Engineering, 5, 64-70. doi: 10.4236/msce.2017.52007.

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