Advances in Chemical Engineering and Science

Volume 2, Issue 2 (April 2012)

ISSN Print: 2160-0392   ISSN Online: 2160-0406

Google-based Impact Factor: 1.22  Citations  

Structural Evolution of Polyacrylonitrile Fibers in Stabilization and Carbonization

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DOI: 10.4236/aces.2012.22032    13,708 Downloads   24,666 Views  Citations

ABSTRACT

The effect of structural evolution polyacrylonitrile (PAN) on mechanical properties was investigated in stabilization and carbonization. PAN spun fibers were stabilized in a convection oven with a constant tension for various times at 250℃. Fourier Transform Infrared spectroscopy (FTIR) and gel fraction results suggested that intra and intermolecular stabilization reactions occurred simultaneously. X-ray diffractograms revealed a disruption of crystalline structure and an appearance of pre-graphitic structure of PAN fibers due to stabilization. These structural changes by stabilization resulted in the significant decrease of tensile properties of fibers. In Raman spectra with heat treated fibers from 400℃ up to 1200℃, the intensity ratio of the D to G bands (ID/IG) decreased as heat treatment temperature increased, indicating an increase of basal plane of graphitic layer of heat treated fibers. Tensile strength of heat treated fibers at 1200℃ was found to be as high as 2.2 GPa.

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Lee, S. , Kim, J. , Ku, B. , Kim, J. and Joh, H. (2012) Structural Evolution of Polyacrylonitrile Fibers in Stabilization and Carbonization. Advances in Chemical Engineering and Science, 2, 275-282. doi: 10.4236/aces.2012.22032.

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[211] Investigation of Progress of Reactions and Evolution of Radial Heterogeneity in the Initial Stage of Thermal Stabilization of PAN Precursor Fibres
Polymer Degradation and Stability, 2016
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Composites Part B: Engineering, 2015
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[229] Improvement of the cycling performance of LiCoO 2 with assistance of cross-linked PAN for lithium ion batteries
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