Organic Melt Crystallization as a Method for Synthesis of Supramolecular Complexes - Advances in Chemical Engineering and Science

ACES > Vol.6 No.2, April 2016

Advances in Chemical Engineering and Science

Volume 6, Issue 2 (April 2016)

ISSN Print: 2160-0392 ISSN Online: 2160-0406

Google-based Impact Factor: 1.41 Citations h5-index & Ranking

Organic Melt Crystallization as a Method for Synthesis of Supramolecular Complexes ()

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DOI: 10.4236/aces.2016.62009 2,258 Downloads 3,153 Views Citations

Author(s)

Masaaki Yokota^*, Ryota Nakamura, Norihito Doki

Affiliation(s)

Department of Chemistry and Bioengineering, Iwate University, Morioka, Japan.

ABSTRACT

The most simple method for solventless synthesis of supramolecular complex of CMCR·2BPY·BZP, [CMCR = C-methylcalix[4]resorcinarene, BPY = 4,4'-bipyridine, BZP = benzophenone], is proposed. Although CMCR by itself is high melting point compound (above 300°C), CMCR was found to be dissolved in melt mixture of BPY and BZPeven below 120°C. In the mixture of the three components, the reaction occurs to form CMCR·2BPY·BZP supramolecular complex.

KEYWORDS

Organic Melt Crystallization as a Method for Synthesis of Supramolecular Complexes

Share and Cite:

Yokota, M. , Nakamura, R. and Doki, N. (2016) Organic Melt Crystallization as a Method for Synthesis of Supramolecular Complexes. Advances in Chemical Engineering and Science, 6, 76-81. doi: 10.4236/aces.2016.62009.

Cited by

[1]	Fast, Facile and Solvent‐Free Dry‐Melt Synthesis of Oxovanadium (IV) Complexes: Simple Design with High Potency towards Cancerous Cells
	2019

[2]	Fast, facile and solvent‐free dry melt synthesis of oxovanadium (IV) complexes: Simple design with high potency towards cancerous cells
	2019

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