TITLE:
Some Salicylato New Organotin (IV) and Copper Chloride Adducts and Derivative: Synthesis and Spectroscopic Study
AUTHORS:
Boucar Diouf, Waly Diallo, Bocar Traoré, Mamadou Sidibé
KEYWORDS:
Discrete Structures, Hydrogen Bonds, Monochelating Monodentate, Octahedral or Tetrahedral Environments
JOURNAL NAME:
Journal of Materials Science and Chemical Engineering,
Vol.12 No.10,
October
24,
2024
ABSTRACT: Three new salicylate complexes and derivatives have been synthesized and studied by infrared, 119Sn NMR and UV-visible spectroscopies. The suggested structures for the two compounds are discrete with NH-O and NH-Cl hydrogen bonds. The salicylate oxyanion is monochelating for the first salicylate compound with an octahedral tin (IV) centre and monodentate for the second salicylate compound, the environments around the tin centre being tetrahedral. For the cooper complex, the salicylate ligand is monochelating and the environments around the copper atom centre are tetrahedral.