TITLE:
Organic Compounds Possessing the Plastic Crystalline Phase: Calculation of Their Fusion Enthalpies
AUTHORS:
Mikhail Yu. Gorbachev, Natalia N. Gorinchoy
KEYWORDS:
Fusion Enthalpies Calculation, Organic Compounds, Inorganic Compounds, Plastic Crystalline Phases
JOURNAL NAME:
International Journal of Organic Chemistry,
Vol.14 No.3,
September
10,
2024
ABSTRACT: For the first time, for different organic and inorganic compounds possessing the plastic crystalline phase, a new semiempirical equation describing dependence of their fusion enthalpies on such physico-chemical quantities as normal melting temperature, surface tension, molar volume and critical molar volume is received on the base of the principle of corresponding states and the energy equipartition theorem. Moreover, the proposed equation allows one to take into account the particularities of one-particle molecular rotation in the plastic crystalline phase.