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Bystrov, N.S., Dobrynin, V.N., Kolosov, M.N., Popravko, S.A. and Chernov, B.K. (1978) Chemistry of Hyperforin. IX. The Structure of Hyperforin. Bioorganicheskaya Khimiya, 4, 948-955.
has been cited by the following article:
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TITLE:
Super Antibiotics, Part IV. Hyperforin, Relative and Absolute Stereochemistry Elucidated by Gas-Chromatography Mass-Spectrometry with Supersonic Molecular Beams
AUTHORS:
Ilia Brondz
KEYWORDS:
Hyperforin, Perforatrin, Relative and Absolute Stereochemistry, Gas Chromatography-Mass Spectrometry, Chirality
JOURNAL NAME:
International Journal of Analytical Mass Spectrometry and Chromatography,
Vol.5 No.3,
September
22,
2017
ABSTRACT: Relative and absolute stereochemistry for hyperforin has been proposed by Brondz et al. was supported and new isomer of hyperforin-perforatrin has been discovered. Relative and absolute stereochemistry for perforatrin was proposed and elucidated by using gas-chromatography mass-spectrometry with supersonic molecular beams (SMB). The possibility of the existence of ambiguities in chirality as a hypothesis for the existence, and a new understanding, of chiral substances with shifting chirality is presented.