TITLE:
MLA-Based Detection of Organic Matter with Iodized Epoxy Resin—An Alternative to Carnauba
AUTHORS:
Anne Rahfeld, Jens Gutzmer
KEYWORDS:
SEM-Based Image Analysis, Epoxy Resin, Iodoform, Organic Matter, Kupferschiefer
JOURNAL NAME:
Journal of Minerals and Materials Characterization and Engineering,
Vol.5 No.4,
July
5,
2017
ABSTRACT: Solid organic matter is an important constituent not only in coal, but also in black shale-hosted ore deposits. The reliable recognition and quantification of organic carbon—as well as its microfabric relation to associated inorganic minerals—plays a crucial role in characterization by scanning electron microscopy-based image analysis. However, the use of conventional epoxy resin in the preparation of grain mounts does not allow for recognition of solid organic carbon compounds. In this study we illustrate that the use of iodized epoxy resin readily overcomes this bottleneck. Best results are obtained with an addition of 15 wt% iodoform to the epoxy resin. With process samples of black shale-hosted polymetallic Kupferschiefer-type ore as a case study, it is shown that recognition and quantification of solid organic carbon are easily achieved and that tangible parameters such as particle and grain sizes, association and liberation for ore and gangue minerals can be determined in the presence of solid organic matter. Due to the inherent uncertainty of the exact chemical composition of the kerogen contained in Kupferschiefer, it was not possible to attain exact comparability between chemical Corg assays and assays calculated from MLA data. However, the results are still found to closely agree with one another. The strength of iodized resin lies in its ability to distinguish organic matter with high hydration ratios in addition to the easy integration in sample preparation. It could therefore be an attractive supplement in the analyses of other raw materials containing complex organic-matter.