Article citationsMore>>
Connolly, T.J., Constantinescu, A., Lane, T.S., Matchett, M., Mcgarry, P. and Paperna, M. (2005) Assessment of a Reductive Amination Route to Methyl(3-nitrobenzyl)amine Hydrochloride. Organic Process Research & Development, 9, 837-842. http://dx.doi.org/10.1021/op050120x
has been cited by the following article:
-
TITLE:
Carbohydrate-Derived Organocatalysts for the Reduction of Imines with Trichlorosilane
AUTHORS:
Xin Ge, Chao Qian, Xinzhi Chen
KEYWORDS:
Carbohydrate, Organocatalyst, Reduction, Imine
JOURNAL NAME:
Journal of Materials Science and Chemical Engineering,
Vol.3 No.6,
June
12,
2015
ABSTRACT:
The backbone of D-glucosamine hydrochloride
was fine-tuned and modified by protecting the hydroxyl groups. In order to
reduce imines with trichlorosilane, the carbohydrate-derived organocatalysts
were prepared and screened. Methyl-4,6-O-benzylidene-2-amino-2-deoxy-α-D-glucopyr
anoside was found as the best catalyst. The reduction was proceeded under CHCl3
as solvent at 40?C, affording 68% - 94% yield.