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Saliba, M., Orlandi, S., Matsui, T., Aghazada, S., Cavazzini, M., Correa-Baena, J.P., Gao, P., Scopelliti, R., Mosconi, E., Dahmen, K.H., De Angelis, F., Abate, A., Hagfeldt, A., Pozzi, G., Graetzel, M. and Nazeeruddin, M.K. (2016) A Molecularly Engineered Hole-Transporting Material for Efficient Perovskite Solar Cells. Nature Energy, 1, Article No. 15017.
has been cited by the following article:
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TITLE:
Arsenic and Chlorine Co-Doping to CH3NH3PbI3 Perovskite Solar Cells
AUTHORS:
Tsuyoshi Hamatani, Yasuhiro Shirahata, Yuya Ohishi, Misaki Fukaya, Takeo Oku
KEYWORDS:
Perovskite, Arsenic, Solar Cell, NH4Cl, Chlorine
JOURNAL NAME:
Advances in Materials Physics and Chemistry,
Vol.7 No.1,
January
11,
2017
ABSTRACT: Arsenic (As) and chlorine (Cl) were co-doped to CH3NH3PbI3 perovskite solar cells, and the photovoltaic properties were investigated. AsI3 and NH4Cl were added to perovskite precursor solution, which were deposited on mesoporous TiO2 by a spin-coating combining an air flow method. Current density-voltage characteristics and incident photon-to-current conversion efficiencies were improved by the co-doping of As and Cl to the perovskite phase, which also indicated an energy gap of 1.57 eV. X-ray diffraction showed suppression of PbI2 formation by the AsI3 addition. The structure analysis by scanning electron microscopy indicated formation of a homogeneous microstructure by adding AsI3 with NH4Cl, which would result in the improvement of the photovoltaic properties.
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