TITLE:
Kinetics on Thermal Decomposition of Iron(III) Complexes of 1,2-Bis(Imino-4’-Antipyrinyl)Ethane with Varying Counter Anions
AUTHORS:
Fikre Elemo, Tesfay Gebretsadik, Mamo Gebrezgiabher, Yosef Bayeh, Madhu Thomas
KEYWORDS:
Iron(III) Complexes, 1, 2-Bis(Imino-4’-Antipyrinyl)Ethane, Thermal Decomposition, Kinetics
JOURNAL NAME:
Advances in Chemical Engineering and Science,
Vol.9 No.1,
December
5,
2018
ABSTRACT: A comparative thermal decomposition kinetic investigation on Fe(III) complexes of a antipyrine Schiff base ligand, 1,2-Bis(imino-4’-antipyrinyl)ethane (GA)), with varying counter anions viz. CIO4-, NO3-, SCN-, Cl-, and Br-,
has been done by thermogravimetric analysis by using Coats-Redfern equation. The kinetic parameters like activation energy (E),
pre-exponential factor (A) and entropy of activation (ΔS) were
quantified. On comparing the various kinetic parameters, lower activation energy was observed in second stage as compared to first thermal decomposition stage. The same trend has been observed for pre-exponential factor (A) and entropy of activation (ΔS). The present results show that the starting materials having higher activation energy (E), are more stable than the intermediate products, however; the intermediate products possess well-ordered chemical structure due to their highly negative entropy of activation
(ΔS) values. The present investigation proves that the counter anions play an important role on the thermal decomposition kinetics of the complexes.