Crystallization in the Three-Component Systems Rb2SO4-MSO4-H2O (M = Mg, Co, Ni, Cu, Zn) at 298 K

Abstract

The crystallization in the three-component systems Rb2SO4-MSO4-H2O (M = Mg, Co, Ni, Cu, Zn) is studied by the method of isothermal decrease of supersaturation. It has been established that isostructural double compounds,

Rb2M(SO4)2·6H2O (M = Mg, Co, Ni, Cu, Zn), , crystallize from the ternary solutions within wide

concentration ranges. The infrared spectra are discussed with respect to the normal vibrations of the sulfate ions and water molecules. The unit-cell group theoretical treatment of the double salts is presented. The extent of energetic distortions of guest ions (about 2 mol%) matrix-isolated in the respective selenates, (M' = K, Rb, ; M" = Mg, Co, Ni, Cu, Zn), is commented.

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V. Karadjova and D. Stoilova, "Crystallization in the Three-Component Systems Rb2SO4-MSO4-H2O (M = Mg, Co, Ni, Cu, Zn) at 298 K," Journal of Crystallization Process and Technology, Vol. 3 No. 4, 2013, pp. 136-147. doi: 10.4236/jcpt.2013.34022.

Conflicts of Interest

The authors declare no conflicts of interest.

References

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