Boron Removal by Electrocoagulation Using Full Factorial Design

Khaoula Missaoui, Wided Bouguerra, Chiraz Hannachi, Béchir Hamrouni

UR11ES17 Traitement et Dessalement des Eaux, Faculté des Sciences de Tunis, Université de Tunis El Manar, Tunis, Tunisie.

DOI: 10.4236/jwarp.2013.59088                

Abstract

Saline waters treatment has become increasingly important for drinking water supply in a greater part of the world. However, some serious limitations had recently been discovered during water treatment, among them the boron problem seems to have a critical meaning. According to the WHO regulations (2011), the boron concentration should be reduced to less than 2.4 mg/L for drinking water. The purpose of this study is to investigate the feasibility of electrocoagulation (EC) as a pretreatment process to remove boron from saline waters. To optimize the experimental conditions of boron removal, the effects of some parameters were studied such as inter-electrode distance (d_ie), electrode connection mode, (S/V) ratio, pH_i and initial conductivity of the solution (σ_i). Subsequently, an experimental design methodology was implemented to evaluate statistically the most significant operating parameters. The effects of current density, EC time and initial boron concentration and their mutual interaction were investigated using 2³ full factorial design. At optimal conditions, boron removal from synthetic aqueous solutions containing initial boron concentrations of 5 and 50 mg/L reached 81% and 79%, respectively. Applied to boron removal from seawater samples, EC reduces boron concentration to less to 2.4 mg/L with excessive energy consumption under optimal parameters.

Keywords

Boron Removal; Electrocoagulation; Full Factorial Design

Conflicts of Interest

The authors declare no conflicts of interest.

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