Supercapacitor Consisting of a Form Core Sandwich with Woven Carbon Fiber Skin

Abstract

Structural capacitors are composite structures that function as energy storage capacitors. Parallel plate-type capacitors have the advantage of high voltage resistance, but are limited by low capacitance. An electric double-layer capacitor with a composite structure using a solid polymer electrolyte matrix with a glass fiber fabric separator has recently been developed. However, the solid polymer electrolyte caused the capacitor to possess high internal resistance. In the present study, a new design of supercapacitor using a form core sandwich with high water retention is proposed and experimentally investigated. Activated carbon sheets are used as electrodes on the form core sandwich to make a supercapacitor. Woven carbon fabric is used as lead wires of the supercapacitor. The resulting supercapacitor displays a low surface resistance of 810 Ωcm2 and high areal capacitance of 520 mF/cm2.

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Todoroki, A. , Sawada, T. , Mizutani, Y. and Suzuki, Y. (2015) Supercapacitor Consisting of a Form Core Sandwich with Woven Carbon Fiber Skin. Open Journal of Composite Materials, 5, 101-109. doi: 10.4236/ojcm.2015.54013.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] Gibson, R.F. (2010) A Review of Recent Research on Mechanics of Multifunctional Composite Materials and Structures. Composite Structures, 92, 2793-2810.
http://dx.doi.org/10.1016/j.compstruct.2010.05.003
[2] Luo, X.C. and Chung, D.D.L. (2001) Carbon-Fiber/Polymer-Matrix Composites as Capacitors. Composites Science and Technology, 61, 885-888.
http://dx.doi.org/10.1016/S0266-3538(00)00166-4
[3] Lin, Y.R. and Sodano, H.A. (2009) Characterization of Multifunctional Structural Capacitors for Embedded Energy Storage. Journal of Applied Physics, 106, Article ID: 114108.
http://dx.doi.org/10.1063/1.3267482
[4] Carlson, T., Ordéus, D., Wysocki, M. and Asp, L.E. (2010) Structural Capacitor Materials Made from Carbon Fibre Epoxy Composites. Composites Science and Technology, 70, 1135-1140.
http://dx.doi.org/10.1016/j.compscitech.2010.02.028
[5] Carlson, T., Ordéus, D., Wysocki, M. and Asp, L.E. (2011) CFRP Structural Capacitor Materials for Automotive Application. Plastics, Rubber and Composites, 40, 311-316.
http://dx.doi.org/10.1179/174328911X12948334590286
[6] O’Brien, D.J., Baechie, D.M. and Wetzel, E.D. (2011) Design and Performance of Multifunctional Structural Composite Capacitors. Journal of Composite Materials, 45, 2797-2809.
http://dx.doi.org/10.1177/0021998311412207
[7] Shirshova, N., Qian, H., Shaffer, M.S.P., Steinke, J.H.G., Greenhalgh, E.S., Curtis, P.T., Kucernak, A. and Bismarck, A. (2013) Structural Composite Supercapacitor. Composites Part A: Applied Science and Manufacturing, 46, 96-107.
http://dx.doi.org/10.1016/j.compositesa.2012.10.007
[8] Shirshova, N., Bismarck, A., Carreyette, S., Fontana, Q.P.V., Greenhalgh, E.S., Jacobsson, P., Johansson, P., Marczewski, M.J., Kalinka, G., Kucernak, A.R.J., Sheers, J., Shaffer M.S.P., Steinke E.S. and Wienrich, M. (2013) Structural Supercapacitor Electrolytes Based on Bicontinuous Ionic Liquid-Epoxy Resin System. Journal of Materials Chemistry A, 1, 15300-15309.
http://dx.doi.org/10.1039/c3ta13163g
[9] Qian, H., Kucernak, A.R.J., Greenhalgh, E.S., Bismarck, A. and Shaffer, M.S.P. (2013) Multifunctional Structural Supercapacitor Composites Based on Carbon Aerogel Modified High Performance Carbon Fiber Fabric. Applied Materials and Interfaces, 5, 6113-6122.
[10] Asp, L.E. and Greenhalgh, E.S. (2014) Structural Power Composites. Composites Science and Technology, 101, 41-61.
http://dx.doi.org/10.1016/j.compscitech.2014.06.020
[11] Todoroki, A., Suzuki, K., Mizutani, Y. and Matsuzaki, R. (2010) Durability Estimates of Copper Plated Electrodes for Self-sensing CFRP Composites. Journal of Solid Mechanics and Materials Engineering, 4, 610-620.
http://dx.doi.org/10.1299/jmmp.4.610
[12] Futaba, D.N., Hata, K., Yamada, T., Hiraoka, T., Hayamizu, Y., Kakudate, Y., Tanaike, O., Hatori, H., Yumura, M. and Iijima, S. (2006) Shape-Engineerable and Highly Densely Packed Single-Walled Carbon Nanotubes and Their Application as Super-Capacitor Electrodes. Nature Materials, 5, 987-994.
http://dx.doi.org/10.1038/nmat1782
[13] Yan, J., Wei, T., Shao, B., Ma, F., Fan, Z., Zhang, M., Zheng, C., Shang, Y., Qian, W. and Wei, F. (2010) Electrochemical Properties of Graphene Nanosheet/Carbon Black Composites as Electrodes for Supercapacitors. Carbon, 48, 1731-1737.
http://dx.doi.org/10.1016/j.carbon.2010.01.014

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