Carboxylic Acids and Esters as Scaffold for Cavities in Porous Single Layer Anti-Reflective Coatings of Silica-Titania with Excellent Optical and Mechanical Properties

Abstract

Anti-reflective (AR) single layer of silica-titania (SiO2-TiO2) coatings were obtained from sols containing pyromellitic dianhydride (PMDA) derivatives and Ti and Si precursors on glass substrate by dip-coating method. The coatings showed very high optical quality and the transmission was improved to up to 98.5%. Furthermore, the coatings also presented good mechanical stability.

Share and Cite:

Menezes, E. , König, P. , Jilavi, M. , Oliveira, P. and Alves Júnior, S. (2014) Carboxylic Acids and Esters as Scaffold for Cavities in Porous Single Layer Anti-Reflective Coatings of Silica-Titania with Excellent Optical and Mechanical Properties. Materials Sciences and Applications, 5, 783-788. doi: 10.4236/msa.2014.511078.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] Batista, M.C. and Morales, A. (2003) Silica Antireflective Films on Glass Produced by the Sol-Gel Method. Solar Energy Materials and Solar Cells, 80, 217-225.
http://dx.doi.org/10.1016/j.solmat.2003.06.004
[2] Schüler, A., Dutta, D., de Chambrier, E., Roecker, C., Temmerman, G.D., Oelhafen, P. and Scartezzini, J.-L. (2006) Sol-Gel Deposition and Optical Characterization of Multilayered SiO2/Ti1-xSixO2 Coatings on Solar Collector Glasses. Solar Energy Materials and Solar Cells, 90, 2894-2907.
http://dx.doi.org/10.1016/j.solmat.2006.05.003
[3] Zhang, X., Fujishima, A., Jin, M., Emeline, A.V. and Murakami, T. (2006) Double-Layered TiO2-SiO2 Nanostructured Films with Self-Cleaning and Antireflective Properties. The Journal of Physical Chemistry B, 110, 25142-25148.
http://dx.doi.org/10.1021/jp064442u
[4] Kim, S., Cho, J. and Char, K. (2007) Thermally Stable Antireflective Coatings based on Nanoporous Organosilicate Thin Films. Langmuir, 23, 6737-6743.
http://dx.doi.org/10.1021/la070003q
[5] Wang, X. and Shen, J. (2010) Sol-Gel Derived Durable Antireflective Coating for Solar Glass. Journal of Sol-Gel Science and Technology, 53, 322-327.
http://dx.doi.org/10.1007/s10971-009-2095-y
[6] Cannavale, A., Fiorito, F., Manca, M., Tortotici, G., Cingolani, R. and Gigli, G. (2010) Multifunctional Bioinspired Sol-Gel Coatings for Architectural Glasses. Building and Environment, 45, 1233-1243.
http://dx.doi.org/10.1016/j.buildenv.2009.11.010
[7] Addamo, M., Augugliaro, V., Paola, A.D., Garcia-Lopez, E., Loddo, V., Marci, G. and Palmisano, L. (2008) Photocatalytic Thin Films of TiO2 Formed by a Sol-Gel Process Using Titanium Tetraisopropoxide as the Precursor. Thin Solid Films, 516, 3802-3807.
http://dx.doi.org/10.1016/j.tsf.2007.06.139
[8] Liu, Z., Zhang, X., Murakami, T. and Fujishima, A. (2008) Sol-Gel SiO2/TiO2 Bilayer Films with Self-Cleaning and Antireflection Properties. Solar Energy Materials and Solar Cells, 92, 1434-1438.
http://dx.doi.org/10.1016/j.solmat.2008.06.005
[9] Kesmez, O., Camurlu, H.E., Burunkaya, E. and Arpac, E. (2009) Sol-Gel Preparation and Characterization of AntiReflective and Self-Cleaning SiO2-TiO2 Double-Layer Nanometric Films. Solar Energy Materials and Solar Cells, 93, 1833-1839.
http://dx.doi.org/10.1016/j.solmat.2009.06.022
[10] Nguyen, C.V., Carter, K.R., Hawker, C.J., Hedrick, J.L., Jaffe, R.L., Miller, R.D., Remenar, J.F., Rhee, H.W., Rice, P.M., Toney, M.F., Trollsas, M. and Yoon, D.Y. (1999) Low-Dielectric, Nanoporous Organosilicate Films Prepared via Inorganic/Organic Polymer Hybrid Templates. Chemistry of Materials, 11, 3080-3085.
http://dx.doi.org/10.1021/cm990114d
[11] Lee, B., Oh, W., Yoon, J., Hwang, Y., Kim, J., Landes, B.G., Quintana, J.P. and Ree, M. (2005) Scattering Studies of Nanoporous Organosilicate Thin Films Imprinted with Reactive Star Porogens. Macromolecules, 38, 8991-8995.
http://dx.doi.org/10.1021/ma0501951
[12] Falcaro, P., Malfatti, L., Kidchob, T., Giannini, G., Falqui, A., Casula, M.F., Amenitsch, H., Marmiroli, B., Grenci, G. and Innocenzi, P. (2009) Hierarchical Porous Silica Films with Ultralow Refractive Index. Chemistry of Materials, 21, 2055-2061.
[13] Guillemot, F., Brunet-Bruneau, A., Bourgeat-Lami, E., Gacoin, T., Barthel, E. and Boilot, J.P. (2010) Latex-Templated Silica Films: Tailoring Porosity to Get a Stable Low-Refractive Index. Chemistry of Materials, 22, 2822-2828.
[14] Mellott, N.P., Durucan, C., Pantano, C.G. and Guglielmi, M. (2006) Commercial and Laboratory Prepared Titanium Dioxide Thin Films for Self-Cleaning Glasses: Photocatalytic Performance and Chemical Durability. Thin Solid Films, 502, 112-120.
http://dx.doi.org/10.1016/j.tsf.2005.07.255
[15] Budunoglu, H., Yildirim, A. and Bayindir, M. (2012) Flexible and Mechanically Stable Antireflective Coatings from Nanoporous Organically Modified Silica Colloids. Journal of Materials Chemistry, 22, 9671-9677.
http://dx.doi.org/10.1039/c2jm30804e
[16] ASTM International (2005) Standard Test Method for Film Hardness by Pencil Test, ASTM D3363-05. West Conshohocken.
[17] ASTM International (2009) Standard Test Methods for Measuring Adhesion by Tape Test, ASTM D3359-09e2. West Conshohocken.
[18] Chen, C.H., Li, S.Y., Chiang, A.S., Wu, A.T. and Sun, Y. (2011) Scratch-Resistant Zeolite Anti-Reflective Coating on Glass for Solar Applications. Solar Energy Materials and Solar Cells, 95, 1694-1700.
http://dx.doi.org/10.1016/j.solmat.2011.01.032
[19] Pan, Q., Shen, J., Wang, X. and Zhang, Z. (2011) Antireflective Coatings for Solar Cells Derived from Different Evaporation Solvents. Proceedings of the 5th Shangai International Nanotechnology Cooperation Symposium, Shangai, 30 October-1 November 2011, 10-14.

Copyright © 2023 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.