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Nonlinear Optical Properties and Optical Limiting Measurements of {(1Z)-[4-(Dimethylamino)Phenyl]Methylene} 4-Nitrobenzocarboxy Hydrazone Monohydrate under CW Laser Regime

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DOI: 10.4236/opj.2014.47018    3,422 Downloads   4,395 Views   Citations

ABSTRACT

We report results from the investigation of the nonlinear refractive index and nonlinear absorption coefficient of {(1Z)-[4-(Dimethylamino)phenyl]methylene} 4-nitrobenzocarboxy hydrazone mono-hydrate (DMPM4NBCHM) solution using Z-scan technique with a continuous wave (CW) Argon ion laser. The results show that this type of organic material has a large nonlinear absorption and nonlinear refractive index at 488 nm and 514 nm. The origin of the nonlinear effects was discussed. We demonstrate that the light induced nonlinear refractive index variation, leads to limiting effect. The results indicated that DMPM4NBCHM could be promising candidates for application on nonlinear photonic devices and optical limiters.

Conflicts of Interest

The authors declare no conflicts of interest.

Cite this paper

Henari, F. and Patil, P. (2014) Nonlinear Optical Properties and Optical Limiting Measurements of {(1Z)-[4-(Dimethylamino)Phenyl]Methylene} 4-Nitrobenzocarboxy Hydrazone Monohydrate under CW Laser Regime. Optics and Photonics Journal, 4, 182-188. doi: 10.4236/opj.2014.47018.

References

[1] Nalwa, H.S. and Miyata, S. (1997) Nonlinear Optics of Organic Molecules and Polymers. Chemical Rubber Company, Boca Raton.
[2] Eichler, H.J., Gunter, P. and Pohl, D.W. (1986) Laser-Induced Dynamic Gratings, Vol. 50 of Springer Series in Optical Sciences. Springer-Verlag, Berlin.
[3] Henari, F.Z. (2001) Optical Switching in Organometallic Phythalocyanine. Journal of Optics A: Pure and Applied Optics, 3, 188-190.
http://dx.doi.org/10.1088/1464-4258/3/3/306
[4] Marder, S.R., Torruellas, W.E., Blanchard-Desce, M., Ricci, V., Stegeman, G.I., Gilmour, S., Bredas Li, J., Bublitz, G.U. and Boxer, S.G. (1997) Large Molecular Third-Order Optical Nonlinearities in Polarized Carotenoids. Science, 276, 1233-1236.
http://dx.doi.org/10.1126/science.276.5316.1233
[5] Hache, A. and Bougeois, M. (2000) Ultrafast All-Optical Switching in a Silicon-Based Photonic Crystal. Applied Physics Letters, 25, 4089-4092.
http://dx.doi.org/10.1063/1.1332823
[6] Balamurugaraj, P., Suresh, S., Koteeswari, P. and Mani, P. (2013) Growth, Optical, Mechanical, Dielectric and Photoconductivity Properties of L-Proline Succinate NLO Single Crystal. Journal of Materials Physics and Chemistry, 1, 4-8.
[7] Shen, Y.R. (1984) The Principle of Nonlinear Optics. Wiley, New York.
[8] Sun, X., Yu, G.R.Q., Xu, Q., Hor, T.S. and Jia, A.W. (1998) Broadband Optical Limiting with Multiwalled Carbon Nanotubes. Applied Physics Letters, 739, 3632-3634.
http://dx.doi.org/10.1063/1.122845
[9] Dabby, F.W., Gustafson, T.K., Whinnery, J.R., Kohanzadeh, Y. and Kelley, P.L. (1970) Thermally Self-Induced Phase Modulation of Laser Beam. Applied Physics Letters, 16, 362-366.
http://dx.doi.org/10.1063/1.1653226
[10] Brugioni, S. and Meucci, R. (2002) Self-Phase Modulation in a Nematic Liquid Crystal Film Induced by a Low-Power CO2 Laser. Optics Communications, 206, 445-451.
http://dx.doi.org/10.1016/S0030-4018(02)01486-4
[11] Talebian, E. and Talebian, M. (2012) Accommodation of Theoretical—Experimental Results of Verdet Constant in First Six Groups of Alcohols. Optik, 123, 1807-1809.
http://dx.doi.org/10.1016/j.ijleo.2011.10.041
[12] Vijayakumar, S., Babu, M., Balakrishna, K. and Chandrasekharan, K. (2011) Third-Order Nonlinear Optical Response of Newly Synthesized Accepter/Donor Substituted Propylidene Aryloxy Acet Hydrazide. Optik, 123, 21-25.
http://dx.doi.org/10.1016/j.ijleo.2010.09.051
[13] Serbutoviez, C., Bosshard, C., Knopfle, G., Wyss, P., Pretre, P., Gunter, P., Schenk, K., Solari, E. and Chapuis, G. (1995) Hydrazone Derivatives: An Efficient Class of Crystalline Materials for Nonlinear Optics. Chemistry of Materials, 7, 1198-1206.
http://dx.doi.org/10.1021/cm00054a020
[14] Albota, M., Beljonne, D., Bredas, J.L., Ehrlich, J.E., Fu, J.Y., Heikal, A.A., Hess, S.E., Kogej, T., Levin, M.D., Marder, S.R., McCord-Maughon, D., Perry, J.W., Rochel, H., Rumi, M., Subramaniam, G., Webb, W.W., Wu, X.L. and Xu. C. (1998) Design of Organic Molecules with Large Two-Photon Absorption Cross Sections. Science, 281, 1653-1656.
http://dx.doi.org/10.1126/science.281.5383.1653
[15] Sheik-Bahae, M., Said, A.A., Wei, T.H., Hagan, D.J. and Van Stryland, E.W. (1990) Sensitive. Measurement of Optical Nonlinearities Using Single Beam. IEEE.J.of Quan. Elec. JQE QE, 26, 760-769.
[16] Hoong-Kun, F., Jebas, S.R., Sujith, K.V., Patil, P.S. and Kalluraya, B. (2008) {(1Z)-[4(Dimethylamino) Phenyl]Methylene} 4-Nitrobenzocarboxyhydrazone Monohydrate. Acta Crystallographica, E64, o1907-o1908.
[17] Cuppo, F.L.S., Neto, A.M.F., Gomeze, S.L. and Muhoray, P.P. (2002) Thermal-Lens Model Compared with the Sheik-Bahae Formalism in Interpreting Z-Scan Experiments on Lyotropic Liquid Crystals. Journal of the Optical Society of America B, 19, 1342-1348.
http://dx.doi.org/10.1364/JOSAB.19.001342
[18] Rashidian, M.D., Dorranian, S.A., Darani, S. and Saghafi, M.G. (2009) Nonlinear Responses and Optical Limiting Behavior of Basic Violet 16 Dye under CW Laser Illumination. Optik, 120, 1000-1006.
http://dx.doi.org/10.1016/j.ijleo.2008.05.001
[19] Ghaleh, K.J., Salmani, S., Hossai, M. and Ara, M. (2007) Nonlinear Responses and Optical Limiting of Fast Green FCF Dye under a Low Power CW He-Ne Laser Irradiation. Optics Communications, 27, 551-554.
http://dx.doi.org/10.1016/j.optcom.2006.10.037
[20] Sathiyamoorthy, K., Vijayan, C. and Kothiyal, M.P. (2008) Low Power Optical Limiting in ClAl-Phthalocyanine Due to Self Defocusing and Self Phase Modulation Effects. Optical Materials, 31, 79-86.
http://dx.doi.org/10.1016/j.optmat.2008.01.013
[21] Henari, F.Z. (2012) Optical Nonlinear Properties and Optical Switching of Henna (Lawson) Films. International Journal of Thin Films Science and Technology, 1, 255-260.
[22] Qureshi, F.M., Martin, S.J., Long, X., Bradley, D.D.C., Henari, F.Z., Blau, W.J., Smith, E.C., Wang, C.H., Kar, A.K. and Anderson, H.L. (1998) Optical Limiting Properties of a Zinc Porphyrin Polymer and Its Dimer and Monomer Model Compounds. Chemical Physical, 231, 87-94.
http://dx.doi.org/10.1016/S0301-0104(98)00081-0
[23] Balaji, G., Rekha, R.K. and Ramalingam, A. (2011) Nonlinear Charactrization of Safranin O Dye for Application in the Optical Limiting. Acta Physica Polonica A, 119, 359-363.
[24] Oliveira, L.C. and Zilio, S.C. (1994) Single Beam Time Resolved z Scan Measurements of Slow Absorbers. Applied Physics Letters, 65, 2121.
http://dx.doi.org/10.1063/1.112809

  
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