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Chiral palladium complexes based on derivatives of benzylamine and 2α-hydroxypinan-3-one

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DOI: 10.4236/ns.2010.211147    5,118 Downloads   10,129 Views   Citations

ABSTRACT

Synthesized and characterized new chiral palladium complexes, some of which contain asymmetric donor nitrogen atom. Nitrogen-containing derivatives (+) - and (-)-2α-hydroxypinan-3-one- (1R,2R,5R)-3-(benzylimino)-2,6,6-trimethylbicy- clo[3.1.1]heptane-2-ol (HL1), (1S,2S,3S,5S)-3- (benzylamino)-2,6, 6-trimethylbicyclo[3.1.1]- heptane-2-ol (HL2), (1R,2R,5R)-3-((S)-α-methyl- benzylimino)-2,6,6-trimethylbicyclo[3.1.1]- heptane-2-ol (HL3), (1R,2R,3R,5R)-3-((S)-α-methyl- benzylamino)-2,6,6-trimethylbicyclo[3.1.1]- heptane-2-ol (HL4) -were studied as optically active ligands.

Conflicts of Interest

The authors declare no conflicts of interest.

Cite this paper

Zalevskaya, O. , Gur'eva, Y. , Frolova, L. , Alekseev, I. and Kutchin, A. (2010) Chiral palladium complexes based on derivatives of benzylamine and 2α-hydroxypinan-3-one. Natural Science, 2, 1189-1194. doi: 10.4236/ns.2010.211147.

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