Journal of Analytical Sciences, Methods and Instrumentation
Volume 4, Issue 2 (June 2014)
ISSN Print: 2164-2745 ISSN Online: 2164-2753
Google-based Impact Factor: 1 Citations
Compact Formulation of Redox Systems According to GATES/GEB Principles ()
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ABSTRACT
The Generalized Electron Balance (GEB), together with charge balance and concentration balances, completes the set of equations needed for resolution of electrolytic redox systems. The general formulae for GEB were obtained according to Approach II to GEB, i.e., on the basis of the equation 2?f(O) ? f(H) obtained from elemental balances: f(H) for H, and f(O) for O. Equivalency of the Approach II and the Approach I to GEB was proved for an aqueous solution and a binary-solvent system. On this basis, a compact form of GEB was derived.
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