Journal of Analytical Sciences, Methods and Instrumentation

Volume 4, Issue 2 (June 2014)

ISSN Print: 2164-2745   ISSN Online: 2164-2753

Google-based Impact Factor: 1  Citations  

Compact Formulation of Redox Systems According to GATES/GEB Principles

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DOI: 10.4236/jasmi.2014.42006    3,472 Downloads   5,215 Views  Citations

ABSTRACT

The Generalized Electron Balance (GEB), together with charge balance and concentration balances, completes the set of equations needed for resolution of electrolytic redox systems. The general formulae for GEB were obtained according to Approach II to GEB, i.e., on the basis of the equation 2?f(O) ? f(H) obtained from elemental balances: f(H) for H, and f(O) for O. Equivalency of the Approach II and the Approach I to GEB was proved for an aqueous solution and a binary-solvent system. On this basis, a compact form of GEB was derived.

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Michałowska-Kaczmarczyk, A. and Michałowski, T. (2014) Compact Formulation of Redox Systems According to GATES/GEB Principles. Journal of Analytical Sciences, Methods and Instrumentation, 4, 39-45. doi: 10.4236/jasmi.2014.42006.

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