Synthesis, Spectral Characterization and Ligation of N-[2-(Phenylseleno)ethyl]phthalimide - Journal of Crystallization Process and Technology

JCPT > Vol.3 No.1, January 2013

Journal of Crystallization Process and Technology

Volume 3, Issue 1 (January 2013)

ISSN Print: 2161-7678 ISSN Online: 2161-7686

Citations

Synthesis, Spectral Characterization and Ligation of N-[2-(Phenylseleno)ethyl]phthalimide ()

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Download as PDF (Size: 427KB) PP. 31-34

DOI: 10.4236/jcpt.2013.31005 4,783 Downloads 8,407 Views Citations

Author(s)

Rupali Rastogi, Sanjay Kumar Srivastava, Shikha Asolia, Raymond J. Butcher

Affiliation(s)

Department of Chemistry, Howard University, Washington DC, USA.
School of Studies in Chemistry, Jiwaji University, Gwalior, India.

ABSTRACT

PhSe^-Na⁺ generated in situ by reduction of PhSeSePh, with sodium borohydride on reaction with N-(2-bromoethyl) phthalimide in N₂ atmosphere results in the formation of N-[2-(phenylseleno)ethyl]phthalimide (L¹). The title compound has been characterized by elemental analysis, FT-IR, 1H and 13C NMR techniques. The crystal structure of L¹ has been solved by direct methods and refined by full-matrix least squares. The ligand L¹crystallize in the monoclinic space group. Selenium forms two Se-C linkages, one is due to Se-C_alkyl and the other one to Se-C_aryl. Further, the ligation reaction of L¹ with complex 1 is also explored whose identities are characterized by spectroscopic techniques.

KEYWORDS

Phthalimide; Selenium; Monoclinic; Phenylseleno; Sodium Borohydride

Share and Cite:

R. Rastogi, S. Srivastava, S. Asolia and R. Butcher, "Synthesis, Spectral Characterization and Ligation of N-[2-(Phenylseleno)ethyl]phthalimide," Journal of Crystallization Process and Technology, Vol. 3 No. 1, 2013, pp. 31-34. doi: 10.4236/jcpt.2013.31005.

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