Taking Liyang City of Jiangsu Province as the research object, a water pollution accident diffusion simulation and analysis system, taking WebGIS as the core, was established by taking finite difference method to do the system dynamics water quality model solution. This paper introduces the construction process of the model, the integration of the model with GIS, the interactive application of the system and users and the visual dynamic expression of water pollution accidents. By combining the statistical analysis of the spatial and environmental database in the system, the scientific simulation of the temporal and spatial relationship of the development of water pollution accidents on the client side is realized and providing precise decision support for early warning and control of water pollution diffusion.