International Journal of Nonferrous Metallurgy

Volume 2, Issue 1 (January 2013)

ISSN Print: 2168-2054   ISSN Online: 2168-2062

Google-based Impact Factor: 0.63  Citations  

The Uptake of Copper(II) Ions by Chelating Schiff Base Derived from 4-Aminoantipyrine and 2-Methoxybenzaldehyde

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DOI: 10.4236/ijnm.2013.21001    4,430 Downloads   10,174 Views  Citations

ABSTRACT

The Schiff base, 4-[(2-methoxybenzylidene)amino]-1,5-dimethyl-2-phenyl-1H-pyrizol-3(2H)-one (SB), was used for the first time to adsorb copper(II) ions in aqueous solution. Various parameters such as initial pH, agitation period and different initial concentration of copper(II) ions which influenced the adsorption capacity were investigated. The equilibrium adsorption data for copper(II) ions were fitted to Langmuir, Freundlich and Dubinin-Radushkevish isotherm models. The maximum monolayer adsorption capacity of SB as obtained from Langmuir isotherm was 5.64 mg/g. Kinetic data correlated well with the pseudo second-order kinetic model indicating that chemical adsorption was the rate limiting step.

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Oo, C. , Osman, H. , Fatinathan, S. and Zin, M. (2013) The Uptake of Copper(II) Ions by Chelating Schiff Base Derived from 4-Aminoantipyrine and 2-Methoxybenzaldehyde. International Journal of Nonferrous Metallurgy, 2, 1-9. doi: 10.4236/ijnm.2013.21001.

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