Mannich-Type Reactions of Aldimines and Hetero Diels-Alder Reactions of Aldehydes Catalyzed by Anion-Type Lewis Bases Derived from a Single Molecule - International Journal of Organic Chemistry

IJOC > Vol.2 No.3, September 2012

International Journal of Organic Chemistry

Volume 2, Issue 3 (September 2012)

ISSN Print: 2161-4687 ISSN Online: 2161-4695

Google-based Impact Factor: 1.26 Citations

Mannich-Type Reactions of Aldimines and Hetero Diels-Alder Reactions of Aldehydes Catalyzed by Anion-Type Lewis Bases Derived from a Single Molecule ()

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DOI: 10.4236/ijoc.2012.23028 5,715 Downloads 10,385 Views Citations

Author(s)

Kaori Ishimaru, Daiki Maeda, Kaori Ono, Yuya Tanimura

Affiliation(s)

Department of Chemistry, National Defense Academy, Hashirimizu, Yokosuka, Japan.

ABSTRACT

Mannich-type reactions of aldimines with silyl enolates and hetero Diels-Alder reactions of aldehydes with Danishef-sky’s diene in the presence of anion catalysts derived from proline were performed to afford the corresponding products in high yields.

KEYWORDS

Anion Catalyst; Lewis Base; Proline; Mannich-Type Reaction; Hetero Diels-Alder Reaction

Share and Cite:

Ishimaru, K. , Maeda, D. , Ono, K. and Tanimura, Y. (2012) Mannich-Type Reactions of Aldimines and Hetero Diels-Alder Reactions of Aldehydes Catalyzed by Anion-Type Lewis Bases Derived from a Single Molecule. International Journal of Organic Chemistry, 2, 188-193. doi: 10.4236/ijoc.2012.23028.

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