Author(s)

Seema Agarwal, Dhirendra Kumar Sharma

Department of chemistry, Bundelkhand University, Jhansi, Jhansi, Utter Pradesh, India.

Density, viscosity and sound velocity of six binary liquid mixtures of methanol, ethanol, propanol, butanol, hexanol and octanol with 1,4-dioxane have been measured over the entire range of composition at temperature 303.15K. From the experimental densities, viscosities and sound velocity, the excess molar volume (V^E), deviation in viscosity (Δη) and deviation in isentropic compressibility (ΔK_S) have been calculated. The results have been used to discuss the nature and strength of intermolecular interactions in these mixtures.

Density, Viscosity, Sound Velocity, Excess Molar Volume, Viscosity Deviation, Isentropic Compressibility Binary Mixtures, Alcohols

Agarwal, S. and Sharma, D. (2021) Ultrasonic, Volumetric and Isentropic Compressibility of Binary Mixtures of 1,4-Dioxane with Primary Alcohols at 303.15 K. Open Journal of Physical Chemistry, 11, 168-181. doi: 10.4236/ojpc.2021.113010.