The Boguslawski Melting Model

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DOI: 10.4236/wjcmp.2016.61007    2,970 Downloads   3,691 Views  Citations

ABSTRACT

The anharmonic vibrator, whose expression of potential energy contains second and third powers of coordinates, is treated on the basis of dynamical procedure, which presents the state of motion by means of mean position and mean amplitude of vibration. The divergent statistical integral comes here not into consideration. The free energy is represented through mean atomic displacement and developed in power series, retaining fourth degree. The graphs show that at certain temperature, the minimum in free energy disappears, and the atom escapes from the potential pit. A simple atomic model that represents this phenomenon is proposed and the influence of model dimension and pressure on melting temperature will be presented.

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Kozlovskiy, V. (2016) The Boguslawski Melting Model. World Journal of Condensed Matter Physics, 6, 45-55. doi: 10.4236/wjcmp.2016.61007.

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