Electrodeposition of Palladium Coatings from Iminodiacetate Electrolyte - American Journal of Analytical Chemistry

AJAC > Vol.4 No.11, November 2013

American Journal of Analytical Chemistry

Volume 4, Issue 11 (November 2013)

ISSN Print: 2156-8251 ISSN Online: 2156-8278

Google-based Impact Factor: 1.71 Citations h5-index & Ranking

Electrodeposition of Palladium Coatings from Iminodiacetate Electrolyte ()

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Download as PDF (Size: 1023KB) PP. 642-646

DOI: 10.4236/ajac.2013.411076 3,248 Downloads 4,797 Views Citations

Author(s)

Valeriy S. Kublanovsky, Vasiliy N. Nikitenko, Kostiantyn P. Rudenko

Affiliation(s)

V. I. Vernadskii Institute of General and Inorganic Chemistry NAS Ukraine, Kyiv, Ukraine.

ABSTRACT

The ionic composition of an iminodiacetate electrolyte as a function of solution composition and pH has been deter-mined. The kinetic parameters (exchange currents and apparent transfer coefficients) of the electroreduction of a palla-dium(II) bis-iminodiacetate complex from an electrolyte containing excess ligand have been calculated. It has been shown that the rate of the electrode process is controlled by the diffusion of reduced ions to the electrode surface and by the electron-transfer reaction. The possibility of using iminodiacetate electrolyte for palladium plating for the deposition of fine-crystalline adherent and ductile palladium coatings has been examined.

KEYWORDS

Palladium; Iminodiacetate; Complex Compounds; Electrodeposition; Palladium Coatings

Share and Cite:

V. Kublanovsky, V. Nikitenko and K. Rudenko, "Electrodeposition of Palladium Coatings from Iminodiacetate Electrolyte," American Journal of Analytical Chemistry, Vol. 4 No. 11, 2013, pp. 642-646. doi: 10.4236/ajac.2013.411076.

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