Prof. Sharif Iqbal

Chemistry Department

Clemson University, USA

Email: isharif@clemson.edu

Qualifications

1987-1991 Ph.D., Organo-fluorine Chemistry

1972-1973 M.Sc., Sind University, Pakistan, Organic Chemistry

1969-1972 B.Sc., Sind University, Pakistan, Chemistry

Publications (Selected)

1. N-Halogeno Compounds Part 10, N-Fluoroquinuclidinium Triflate. R.E. Banks and I. Sharif, Journal of Fluorine Chemistry, 41 (1988) 297-300.
2. N-Halogeno Compounds Part 13, N-Fluoroquinuclidinium salts,Synthesis and use as Electrophilic Fluorinating Agents. R.E. Banks and I. Sharif, Journal of Fluorine Chemistry, 55 (1991) 207-214.
3. Synthesis, Characterization, and applications of new Electrophilic fluorinating agents of the N-F class presented at Ruhr University Bochum Germany in Sept. 1991. Journal of Fluorine Chemistry, 54,1-3(1991) 207.
4. 1-Akyl-4-fluro-1, 4-diazoniabicyclo[2.2.2] octane salts: a novel family of power-variable Electrophilic fluorinating agents (selectfluors). R.E.Banks, S.N. Khaffaf, S.Lal, I. Sharif, and R.G. Syret., Chemical. Communication. , 8, 1992, 595-596.
5. The structure of the new Electrophilic fluorinating agent 1–chloromethyl-4-fluoro-1,4-diazoniabicyclo {2.2.2} octane bis (tetrafluoroborate) and two of its monoquaternary analogues. R.E. Banks, I.Sharif, and R.G. Prichard, Acta Crystallographica, c49, 492-495, part 3 March 15 (1993).
6. N-fluoroquinuclidinium trifluoromethane sulfonate (triflate) A novel electrophilic fluorinating agent. Banks R.E., Pritchard R.G., Sharif I. Acta Crystellographica section C-Crystal Structure communications 49; 1806-1807, Part 10 Oct 15 1993.
7. Quinuclidine trifluoro monoborane-A(1/1)Lewis base-Lewis acid complex. Banks R.E., Besheesh MK, Pritchard R.G., Sharif I. Acta Crystellographica section C-Crystal Structure communications 49;1804-1806, Part 10 Oct 15 1993.
8. Transfer fluorination of quinuclidine with F-TEDA-BF4. Abdul-Ghani, M, Banks, R.E , Basheesh, M. K, I. Sharif and R. G. Syvret. J. Fluorine Chemistry, 73,255-257 (1995).
9. N-Halogeno Compounds Part 17. Precursors of N-F TEDA reagents: quaternary salts of 1,4-diazabicyclooctane containing fluoro-anions, and their Lewis acid-Lewis base adducts with Borontrifluoride, phosphorous penta fluoride and sulpher trioxide. R. E. Banks, M.k. Basheesh, S.N. Mohaldin –Khaffaf and I. Sharif. Journal of Fluorine Chemistry, 1996,78,43-50.
10. N-Halogeno compounds. Part 18. 1-Akyl-4-fluoro-1, 4-diazoniabicyclo [2,2,2]octane salts: user-friendly Site Selective Electrophilic fluorinating agents of the N-fluroammonium Class. R.E. Banks, Mohd. K. Basheesh, Suad N. Mohialdin Khaffaf and I. Sharif. Journal of Chemical Society, Perkin Trans 1, 2069-2076 (1996).
11. N-halogeno compounds. 19. Electrophilic fluorinating agents of themultiple mono-N-fluro class derived from nitrogen hetrocycles. R.E. Banks, Mohd. K. Basheesh, Suad N. Mohialdin Khaffaf and I. Sharif. Journal of fluorine Chemistry 81(2) 157-161 March 1997.
12. Advances in TFE-based fluoropolymers for 157-nm lithography: a progressreport. Sharif Iqbal; DesMarteau Darryl; Ford Larry; Shafer Gregory J; ThomasBrian; Conley Will; Zimmerman Paul; Miller Daniel: Lee Guen Su; Chambers Charles; Trinque Brian; Chiba takashi; Osborn Brian; Wilson Grant. Department of Chemistry, Clemson University, Clemson, SC, USA. Proceedings of SPIE-The International society of Optical Engineering (2003), 5039 (Pt. 1, Advances in Resists Technology and processing xx), 33-42
13. Sharif, I., D. DesMarteau, W. Conley, P. Zimmerman, D. Miller, C.R. Chambers, B.C. Trinque, T. Chiba, B.P. Osborn, C.G. Willson, "157nm Resist Based on TFE Polymers", 3rd Intl Conference on 157nm Lithography, Yokohama, Japan August 2003.
14. Willson, C.G., B.C. Trinque, B.P. Osborn, C.R. Chambers, Y.-T. Hsieh, T. Chiba, P. Zimmerman, D. Miller, Sharif, I., D. DesMarteau, and W. Conley, The design of resist materials for 157 nm lithography. Journal of Photopolymer Science and Technology, 2002. 15(4): p. 583-590.
15. DesMarteau,DD Creager,S Rajagopal,R Hallac,PB Geiculescu,OE Sharif,I Rettenbacher,A Mei,H. FLUO 23-Fluoroalkyl sulfonimides as electrolytes for PEM fuel cells and lithium batteries. 2007, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY vol.233, 973-973.
16. Sharif,I Jiang,WC DesMarteau,DD Creager,SE. FUEL 92-Proton exchange membrane for fuel cell. 2008, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY vol.236, 973-973.
17. Chang Kyu Byun1, Iqbal Sharif , Darryl D. DesMarteau, Stephen E. Creager and Carol Korzeniewski, Infrared Spectroscopy of Bis(perfluoroalkylsulfonyl) Imides Ionomer, Membrane Materials. J.Phys.chem.B,113(18) pp 6299-6304. 2009.
18. Iqbal Sharif, Wanchao Jiang, Stephen Creager, D.D.DesMarteau, Proton Exchange Membrane for Fuel Cell., Submitted for ACS book on Fuel cell chemistry and operation on 01-12-09.
19. Iqbal Sharif, Ii-Mei Jin, Tom Hickman, Stephen Creager, Darryl DesMarteau. Synthesis of trifluoromethylated phosphinic acid based co- and terpolymers: Novel polymers for PEM fuel cell application.
20. Submitted on 08-03-09 to Macromolecules.
21. Iqbal Sharif, Ii-Mei Jin, Tom Hickman, Stephen Creager, Darryl DesMarteau. Synthesis and copolymerization of sodium 2,2,2-trifluoroethyl-3,6-dioxa-Δ7-4-trifluoromethylperfluorooctylphosphonate with tetrafluoroethylene. Submitted to Polymer on 08-03-09
22. Chapter “Fluorinated ionomers and ionomer membranes containing the bis[(perfluoroalkyl)sulfonyl]imide protogenic group”, I. Sharif, Stephen Creager, Darryl DesMarteau. Handbook of Fluoropolymer Science and Technology, Smith, D. W., Jr.; Iacono, S. T.; Iyer, S., Eds. Wiley, 2014, in preparation. (ISBN 9780470079935)