Reductive Acid Leaching of Low Grade Manganese Ores

Abstract

Manganese recoveries from low-grade ores using organic acids as reducing agents were investigated in the present work. The acid leaching potential of both oxalic acid and citric acid were estimated. Manganese leaching amount were measured by using standard manganese curve and estimated by titration method. Effects of various acid concentrations on leaching efficiency were studied. The observed result suggested prominent manganese recovery of 66% by oxalic acid at 2 M concentration whereas citric acid had less effect on leaching showing leaching percentage upto 40% in 6 days. Acid leaching of manganese ore with both the acids gave a comparative data stating that oxalic acid leached better than citric acid.

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A. Das, S. Swain, S. Panda, N. Pradhan and L. Sukla, "Reductive Acid Leaching of Low Grade Manganese Ores," Geomaterials, Vol. 2 No. 4, 2012, pp. 70-72. doi: 10.4236/gm.2012.24011.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] A. P. Das, L. B. Sukla, N. Pradhan and S. Nayak, “Manganese Biomining: A Review,” Bioresource Technology, Hydrometallurgy, Vol. 102, No. 16, 2011, pp. 7381-7387.
[2] A. P. Das, L. B. Sukla and N. Pradhan, “Microbial Recovery of Manganese Using Staphylococcus Epidermidis,” International Journal of Nonferrous Metallurgy, Vol. 1, No. 2, 2012, pp. 9-12.
[3] J. K. Magnuson and L. L. Lasure, “Organic Acid Production by Filamentous Fungi,” Plenum Publishers, New York, 2004, pp. 307-340.
[4] M. Gharabaghi, M. Irannajad and M. Noaparast, “A Re- view of the Beneficiation of Calcareous Phosphate Ores Using Organic Acid Leaching,” Hydrometallurgy, Vol. 103, No. 1-4, 2010, pp. 96-107. doi:10.1016/j.hydromet.2010.03.002
[5] P. K. Sahoo and R. K. Srinivasa, “Sulphating-Roasting of Low Grade Manganese Ore: Optimisation by Factorial Design,” International Journal of Mineral Processing, Vol. 25, No. 1-2, 1989. pp. 147-152. doi:10.1016/0301-7516(89)90061-6
[6] R. N. Sahoo, P. K. Naik and S. C. Das, “Leaching of Manganese from Low-Grade Manganese Ore Using Oxalic Acid as Reductant in Sulphuric Acid Solution,” Hydrometallurgy, Vol. 62, 2001, pp. 157-163. doi:10.1016/S0304-386X(01)00196-7
[7] F. Pagnanelli, G. Furlani, P. Valentini, F. Vegliò and L. Toro, “Leaching of Low-Grade Manganese Ores by Using Nitric Acid and Glucose: Optimization of the Operating Conditions,” Hydrometallurgy, Vol. 75, No. 1-4, 2004, pp. 157-167. doi:10.1016/j.hydromet.2004.07.007
[8] E. Y. Lee, “Leaching of Mn, Co, and Ni from Manganese Nodules Using an Aerobic Bioleaching Method,” Journal of Bioscience and Bioengineering, Vol. 92, 2001, pp. 354-359.
[9] S. Kukrer, N. O. Yigit, G. Civelekoglu and M. Kitis, “Acidic Leaching and Precipitation of Zinc and Manganese from Spent Battery Powders Using Various Reductants,” Journal of Hazardous Materials, Vol. 173, No. 1-3, 2010, pp. 137-143. doi:10.1016/j.jhazmat.2009.08.063
[10] G. M. Gadd, “Fungal Production of Citric and Oxalic Acid: Importance in Metal Speciation, Physiology and Biogeochemical Processes” Advances in Microbial Physiology, Vol. 41, 1999, pp. 47-92. doi:10.1016/S0065-2911(08)60165-4
[11] B. Ghafarizadeh, F. Rashchi and E. Vahidi, “Recovery of Manganese from Electric Arc Furnace Dust of Ferroman- ganese Production Units by Reductive Leaching,” Minerals Engineering, Vol. 24, No. 2, 2011, pp. 174-176. doi:10.1016/j.mineng.2010.11.003
[12] H. F. Su, Y. X. Wen, F. Wang, Y. Y. Sun and Z. F. Tong, “Reductive Leaching of Manganese from Low-Grade Manganese Ore in H2SO4 Using Cane Molasses as Reductant,” Hydrometallurgy, Vol. 93, No. 3-4, 2008, pp. 136-139. doi:10.1016/j.hydromet.2008.01.001
[13] W. Zhang and C. Y. Cheng, “Manganese Metallurgy Review. Part I: Leaching of Ores/Secondary Materials and Recovery of Electrolytic/Chemical Manganese Dioxide,” Hydrometallurgy, Vol. 89, 2007, pp. 137-159. doi:10.1016/j.hydromet.2007.08.0

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