Journal of Minerals and Materials Characterization and Engineering, 2012, 11, 1050-1054
Published Online October 2012 (http://www.SciRP.org/journal/jmmce)
Impact of Swelling Indices of Sokoto Clays on the
Moulding Properties of the Clays in Sand Mixtures
Ihom A. Paul1, Suleiman U. Mohammed1, Nyior G. Bem2
1Department of Metallurgy, Nation al Metallurgical Development Centre, Jos, Plateau State, Nigeria
2Department of Metallurgical and Materials Engineering, Ahmadu Bello University, Zaria, Kaduna State, Nigeria
Received June 28, 2012; revised July 30, 2012; accepted August 10, 2012
ABSTRACT
The Impact of Swelling Indices of Sokoto Clays on the Moulding Properties of the Clays in Sand Mixtures was investi-
gated. Four clays (labeled A, B, C, D) from different locations in Sokoto state of Nigeria were sampled. The sampling
method was that for each deposit five samples were taken at different positions and then mixed together. At the labora-
tory they were washed to remove organic matter and then dried at 110˚C in the oven. A laborato ry ball mill was used to
grind the dried clays. Each of the clay was then sampled fo r the determination of its swelling index. The determination
of the moulding properties of the clays then followed. Only green compression strength, dry compression strength and
green permeability, moulding properties were d etermined. The analysis of the result revealed that clay B has the highest
green and dry strength values it had the highest green compression strength of 71.7 KN/m2 and the highest dry com-
pression strength of 3225.75 KN/m2. Clay B also has the highest swelling index of 60% and very high degree of expan-
siveness when compared to the other three clays. Clay B was follo wed by clay A with swelling index of 25%; the clay
has high green and dry compression strength and a moderate degree of expansiveness. The inability of clay D with
swelling index of 40% to be the next clay to clay B which has th e highest swelling index of 60% among the four clays
in terms of good moulding properties is an indication that high swelling index does not always mean good moulding
properties in clay binders.
Keywords: Effect of Swelling Index; Clay; Sokoto; Properties; Mould Mixtures
1. Introduction
Clays have several pr operties; both chemical and physic-
cal properties. These properties are responsible for the
various areas of application of clays. Clays are used as
ceramic and refractory materials, used in the formulation
of drilling fluids, as binders in foundry moulds, as bind-
ers for iron ore pellets in metallurgy, as catalyst in p etro-
leum refining and production of petrochemicals, soil
remediation, bleaching of oils, clarification of wines etc
[1,2].
Swelling index is one of the properties of clay it has
generated a lot of investigation in the science and engi-
neering world because of its vital links to areas of appli-
cation of clay. In a work carried out by Paul, et al. [1]
and RMRDC [2], the authors said that clays swell in wa-
ter, creating a thixotropic gel (particularly benton ite) as a
consequence of interlayer water adsorption. The numer-
ous flakes and their extreme fineness contribute to the
many of the industrial uses of clays while their separation
by water molecules cause the well known expansion in
volume of the mass called swelling index which creates
the famous bellying viscosity properties which are essen-
tial in oil drilling applications. The large surface areas of
the particle promote adhesion and bond strength when
mixed with inert materials like sand. The authors were
able to show that swelling index affects green compres-
sion strength, dry compression strength, flowability and
other properties, but could not show any correlation be-
tween swelling index and strength properties of clay
bonded mould. Swelling index is linked to the exchange-
able cat ions in clays these cations are sodium, calcium,
magnesium, hydrogen and potassium, and the amount
and types of these exchangeable cations influence the
surface chemistry of the clay while the charge determines
how the bentonite particles interact while in aqueous
suspension. This interaction is very important in the de-
velopment of bond strength of clays in moulding mix-
tures [3]. Also the large surface area of clay particles
populated with these exchangeable ions give intense re-
sponse to electrolytes in the surrounding water. Paul, et
al. [2], and Paul, et al. [4] said in their works that there
are other properties of clays in slurry form which are
tested to give a measure of effectiveness in sand mixtures
for mould making these include flowability, green and

I. A. PAUL ET AL. 1051
dry strengths, mouldability index, shatter index, com-
pactability, bulk density, permeability and others. The
authors in their various works investigated swelling in-
dex and tried to link it to moulding properties of sand
mixtures. No clear relat i onship was however esta b l ished.
Mittal and Shukla [5] analysed how critical this prop-
erty of clay called swelling index is and outlined in de-
tails how it can be measured. A lot of interest has been
generated on local raw materials sourcing for foundry
shops and in particular clay. This informed the reason for
this study. The obj ective of th is work is to investigate th e
impact of swelling index of four clays on the moulding
properties of the clays in sand mixtures.
2. Materials and Methods
2.1. Materials
Materials used for the research included, four (4) differ-
rent clay samples which were collected from Sokoto state
of Nigeria, kerosene oil from the filling station in
Jos-Nigeria, distilled water from the analytical laboratory
of NMDC Jos, and foundry sand from the foundry re-
search shop of NMDC Jos.
2.2. Equipment
The equipment used were, sieve-425-micron IS sieve,
oven, balance accurate to 0.01 g weighing, graduated
glass cylinders, each 100 ml capacity, sand rammer, elec-
tric permmeter, universal strength testing machine, labo-
ratory ball mill , washing basi ns, filt ering cloth, and m ixer.
2.3. Methods
2.3.1. Swelling Index
The four clays sampled from So koto state using standard
sampling techniques were washed and dried in the oven
at 110˚C. The dried clays were then pulverized using
laboratory ball mill and was ready for use without any
treatment. 50 g of each of the clay sample was dried in
the oven at 100˚C - 110˚C, it was then sieved through
425-micron-IS sieve. Two specimens of each clay weigh-
ing 10 g were taken. Two cylin ders were taken one filled
with kerosene and the other was filled with distilled wa-
ter up to 90 ml capacity. The samples were then poured
gently, one portion into the kerosene the other portion
into the distilled water. This was done for the four clays.
The entrapped air was removed by gently shaking and
stirring with a clean glass rod. The clays were allowed to
stand for 24 hrs. The final (constant) volume of the clay
specimen (not that of the liquid) in both the cylinders
was read. Kerosene is a non-polar liquid causing no
swelling of the clay. The level of the clay specimen in
the graduated cylinder containing kerosene oil, was read
as original volume of the clay sample. The level of the
clay specimen in the second cylinder containing distilled
water was taken as the free swelling level. Precautions
taken during the experiment included, pouring the clay
specimen in both the graduated glass cylinder gently, so
that no clay particle remains stuck to the wall of the cyl-
inder, sufficient time was given to the clay specimens to
attain final equilibrium position of volume without any
further change in the clay volumes. This took more than
24 hours, and the cylinder s used were spaciou s enough to
accommodate the volume increase.
2.3.2. M oulding Properties T e st i n g
Moulding mixture made up of 8% of each clay in turn
and water was prepared using a sand mixer made by
Ridsdale and Dietert Company limited England. The water
was varied from 2% to 6%. The time for mixing every
moulding mixture was kept constant at 15 minutes with
the cover of the mixer closed to avoid moisture loss. Af-
ter every batch the discharge slot was removed and the
moulding mixture was discharged into a plastic container
and immediately transferred to the weighing balance
where the specimen was weighed and poured into the
specimen tube using the pouring hopper. It was then
taken to the sand rammer where it was rammed three
times for the preparation of the standard test specimen 2
inches × 2 inches (50 mm × 50 mm). Specimens for per-
meability were transferred to the electric permmeter
without removing them from the specimen tube for test-
ing, while those for green compression strength were
removed and tested using the universal strength testing
machine made by Ridsdale and company limited. The
specimens for dry compression strength were removed
and dried in the oven at 105˚C and allowed to cool before
testing them using th e universal streng th testing machine.
To ensure accuracy a minimum of two specimens were
used for each test conducted and the average was used.
3. Results and Discussion
3.1. Results
The results of the work are as shown in Table 1 and Fig-
ures 1-4.
3.2. Discussion
Table 1 is the swelling indices of the four clays labeled A,
B, C, and D with swelling index of 25%, 60 %, 10%, and
40% in that order. The same Table 1 shows that clay A
have a degree of expansiveness that is moderate, the de-
gree of expansiveness of clay B is very high, that of clay
C is very low, and that of clay D is high. The table has
clearly shown that swelling index is reflected in the de-
gree of expansiveness the higher the swelling index, the
higher the degree of expansiveness. This observation has
been made by several researchers in the past, the re-

I. A. PAUL ET AL. 1052
Table 1. Investigated swelling indices of sokoto clays.
Sample identityABCD
Swelling index25601040
Degree of
expansivenessModerateV er y highLowHigh
Figure 1. M oulding properties of clay A with swelling index
of 25%.
Figure 2. M oulding properties of clay B with swelling index
of 60%.
Figure 3. M oulding properties of clay C with swelling index
of 10%.
searchers in their different work have also said that
swelling index is reflected in the degree of expansiveness
of the clay [4-6].
Now it has been establish ed that th ere is a positiv e co r-
relation between swelling index and degree of expan-
siveness. The question then is what effect does swelling
index have on the moulding properties of these clays? If
the effect is positive it then means that the selection of
clays for foundry u se as binder for mould making can be
Figure 4. M oulding properties of clay D with swelling index
of 40%.
based on the swelling index and by extension the degree
of expansiveness since the two are related. Let’s now
examine Figures 1-4 to see the impact of swelling index
on the moulding properties of the Sokoto clays.
Figure 1 shows the moulding properties of Sokoto
clay A with swelling index of 25% the moulding proper-
ties plotted are, green compression strength, dry com-
pression strength, and green permeability. According to
Beeley [7] the dry strength pro perties of the clays will be
a reflection of the nature of the clay (sodium-based ben-
tonite, calcium-based bentonite, mixed bentonite, kao-
linitic clay etc.). Sodium bentonite clays tend to have
higher dry strengths than calcium bentonites and the
other type of clays. The green compression strength
curve of Figure 1 of clay A with swelling index of 25%
is lower than that of Figure 2 for clay B with swelling
index of 60%, it is higher than the curve of green com-
pression strength of Figure 3 for clay C with swelling
index of 10%, and it is still higher than that of the green
compression strength of Figure 4 for clay D with swell-
ing index of 40%. Comparing the green compression
strength of the four clays it can be seen that between
moisture content of 2% to 3% clay A has higher values
of green compression strength i.e. 69 KN/m2 and 62.1
kN/m2 as the moisture content is increased to 6% the
values for the green compression strength of clay B re-
mained higher than the other three clays throughout. Re-
lating the values of swelling indices of the clays and the
green compression values it can be said that clay B has
higher moisture absorption capacity than the other clays.
At 4% moisture it had a green compression strength of
70.3 kN/m2, at 5% moisture content it has a green com-
pression strength of 71.7 kN/m2 and at 6% moisture con-
tent it has green co mpression strength of 62.1 kN/m2, the
green compression strength dropped at 6% moisture an
indication that the clay was gradually exceeding its water
absorption limi t [3,7,8].
Let’s now look at dry compression strength of Figure
1 and relate it to the other Figures, the dry compression
strength curve of Figure 1 is higher than that of Figures
3 and 4. Figures 2 which is the plot of moulding proper-

I. A. PAUL ET AL. 1053
ties of clay A shows that the curve of dry compression
strength is higher than the other clays in Figures 1, 3 and
4; Figure 4 is the least. Clay B with a swelling index of
60% and very high degree of expansiveness has consis-
tently maintained high strength values both in the green
and dry states. Clay B is followed by clay A which has a
swelling index of 25% and a moderate degree of expan-
siveness. As mentioned above clay D which has a swell-
ing index of 40% and a high degree of expansiveness has
the least in terms of dry compression strength. As men-
tioned earlier the four clays are different and therefore do
not show any relationship between swelling index and
dry compression strength. The nature and type of clay
determines its properties, it’s obvious that clay B is so-
dium bentonite. The clay was plastic, has very high de-
gree of expansiveness, high swelling index and high wa-
ter absorption capacity which is typical of sodium ben-
tonite clays [6,9,10].
The permeability curve of Figure 1 is more or less the
same with that of Figures 2 and 3 that of Figure 4 is
slightly higher than that of Figure 1. All the four clays
have high permeability which is even ideal for steel
casting. For nonferrous casting p ermeability valu es in the
range of 0 - 80 are ideal, however, for steel casting
higher permeability values are required for gas escape
(100 and above) [9,10].
The analysis of the results have not shown any clear
relationship between the swelling indices of the clays and
the green compression strength of the clays, no relation-
ship is also seen between the swelling index and the dry
compression strength of the clays. Beeley [7] in his work
on clays said maximum swelling power is obtained in the
sodium or sodium treated bentonites: these are notable
for the high level of dry strength which they confer,
whilst the calcium bentonites give maximum green
strength. The scope of this work does not include the
identification of the type of clay, because of that it is
difficult to say that the clays with high swelling indices
are sodium bentonites, but clay B is likely to be a sodium
bentonite while clay A may be calcium bentonite. Clays
C and D may be kaolin or low grade calcium bentonite or
even illite clay. Despite the high swelling index exhibit
by clay D it did not have the high plasticity exhibited by
clay B this was observed during the experiment. Clays B
and A with swelling indices of 60% and 25%, have the
highest strength values, the strength values were higher
than the other clays both in the green and dry conditions.
With this study we agree with several authors [11-13]
who say that the strength of clays in moulding mixtures
depend on the nature of the clay, the exchangeable ions
present and the moisture content these parameters deter-
mine the strength of the bond formed between the clay
particles, the sand grains and the water molecules. The
swelling index might be an indication of good binding
clay, but indicates more the capacity of clay to absorb
moisture [14]. Rundman [15] have used two models to
explain the strength property of clays in moulding mix-
ture and none of these models relate to the swelling index,
the two models are a low moisture model involving po-
larized water molecules on both clay and sand and a high
moisture model involving ionic bonds between the so-
dium ions and the water molecules. The polar bonding at
low moisture is referred to as rigid water bonding and the
ionic water bonding at high moisture is referred to as
bridge bonding. The polar bonds are thought to be quite
weak and are very temperature dependent, while the
ionic bonds are relatively strong and therefore less tem-
perature dependent. Confirmation of the model comes
when the adsorbed ionic species are removed from the
clay by an ion exchange process; the result is the room
temperature properties at high moisture dropping rapidly
to zero. The ionic model is what was observed in clay B
when the moisture content was above 3% the compres-
sion strength values increased indicating stronger bridge
bonding.
We can therefore draw these inferences that the clays
do not show any clear relationship between the swelling
index and the moulding properties, and that the clays are
not the same to give a consistent result for analysis. Dif-
ferent clays have different moulding properties in green
and dry state [16]. Among the four clays clay B has the
highest green compression strength of 71.7 KN/m2 and
highest dry compression strength of 3225.75KN/m2.
4. Conclusions
The study has shown that the clays are not the same type
and therefore a generalized relationship between the
swelling index and the moulding properties can not be
established. Based on this premise the following conclu-
sions have been draw n:
1) The study has not shown any relationship between
swelling index and the moulding prop erties determined
2) The study have shown that the strength properties
depend more on the bonding properties of the clays and
not the swelling index
3) Clay B with the highest swelling index (60%) has
the highest green co mpression strength and dry co mpres-
sion strength properties.
4) The clays (A and C) with moderate and low degree
of expansiveness have higher green and dry strength
properties than the clay D with high degree of expan-
siveness.
5) The moulding properties of clay B is typical of so-
dium bentonite clay
6) The moulding properties of clays A, C and D is
typical of calcium bentonite and kaolin clays
7) Clays with high swelling index also have high de-
gree of expansion.

I. A. PAUL ET AL. 1054
5. Acknowledgement
The authors sincerely acknow ledge the Centre for allow-
ing them to use the facilities in their fou ndryshop for this
work.
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