TITLE:
An Efficient α-Phosphoryloxylation of Ketones
AUTHORS:
Ye Pu, Jie Yan
KEYWORDS:
α-Phosphoryloxylation, Ketol phosphate, (Diacetoxyiodo)benzene, Synthesis
JOURNAL NAME:
International Journal of Organic Chemistry,
Vol.1 No.1,
March
18,
2011
ABSTRACT: An efficient α-phosphoryloxylation of ketones has been developed. When ketones were treated with (diace-toxyiodo)benzene and phosphates in CH2Cl2 at room temperature, the α-phosphoryloxylaction of ketones was easily be carried out, providing the ketol phosphates in good yields.