Shi, D., Adinolfi, V., Comin, R., Yuan, M., Alarousu, E., Buin, A., Chen, Y., Hoogland, S., Rothenberger, A., Katsiev, K., Losovyj, Y., Zhang, X., Dowben, P.A., Mohammed, O.F., Sargent, E.H. and Bakr, O.M. (2015) Low Trap-State Density and Long Carrier Diffusion in Organolead Trihalide Perovskite Single Crystals. Science, 347, 519-522.
https://doi.org/10.1126/science.aaa2725

has been cited by the following article:

• TITLE: Arsenic and Chlorine Co-Doping to CH3NH3PbI3 Perovskite Solar Cells

  AUTHORS: Tsuyoshi Hamatani, Yasuhiro Shirahata, Yuya Ohishi, Misaki Fukaya, Takeo Oku

  KEYWORDS: Perovskite, Arsenic, Solar Cell, NH4Cl, Chlorine

  JOURNAL NAME: Advances in Materials Physics and Chemistry, Vol.7 No.1, January 11, 2017

  ABSTRACT: Arsenic (As) and chlorine (Cl) were co-doped to CH3NH3PbI3 perovskite solar cells, and the photovoltaic properties were investigated. AsI3 and NH4Cl were added to perovskite precursor solution, which were deposited on mesoporous TiO2 by a spin-coating combining an air flow method. Current density-voltage characteristics and incident photon-to-current conversion efficiencies were improved by the co-doping of As and Cl to the perovskite phase, which also indicated an energy gap of 1.57 eV. X-ray diffraction showed suppression of PbI2 formation by the AsI3 addition. The structure analysis by scanning electron microscopy indicated formation of a homogeneous microstructure by adding AsI3 with NH4Cl, which would result in the improvement of the photovoltaic properties.