The Visible and Infrared Multispectral Imager (VIMI) is one of the main payloads of the GF-5 satellite. It has 12 spectral bands covering the wavelength from visible light to thermal infrared. The imager designed life is 8 years. In order to monitor and correct the radiometric performance of the imager for a long time and meet the user’s demand for the quantitative remote sensing application, the expandable diffuser used for calibration in full FOV and full optical path method is designed. The solar diffuser is installed on the front side of the optical system and does not affect the normal imaging of VIMI. When VIMI need calibration, the diffuser is expand to the front of optical system via the driving mechanism. According to the characteristics of the GF-5 satellite orbit, the requirement of the calibration energy and the installation matrix of the imager relative to the satellite, the expansion angle of the diffuser is 39 degrees. The 430 mm × 430 mm large-size PTEE diffuser is manufactured to ensure full FOV and full optical path calibration. The diffuser’s directional hemispherical reflectance is higher than 95% from 420 nm to 2400 nm and variation of BRDF in the direction of imager observation is better than 2.5%. The diffuser stability monitoring radiometer is designed to monitor the on-orbit attenuation performance of the diffuser. Results of ground simulation experiments and preliminary on-board calibration experiments were introduced.