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has been cited by the following article:

• TITLE: Synthesis and Characterization of Two Cu(II) Nitronyl Nitroxide Complexes

  AUTHORS: Youjuan Zhang, Caiwen Zhang, Jing Chen

  KEYWORDS: Nitronyl Nitroxide, Copper Complex, Cyclic Metal-Radical, Synthesis, Characterization

  JOURNAL NAME: Open Journal of Inorganic Chemistry, Vol.11 No.3, June 15, 2021

  ABSTRACT: Two new nitronyl nitroxide Cu(II) complexes {[Cu(hfac)2]2(NIT-4PyPh)}2(1) and [Cu(hfac)2][(NIT-3PyPh)2](2)(NIT-4PyPh=2-[4-(4-pyridinylmethoxy) phenyl]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide,NIT-3PyPh=2-[4-(3-pyridinylmethoxy)phenyl]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide,hfac=hexafluoroacetylacetone), have been synthesized and characterized. The X-ray crystal structure analyses show that structures of the two complexes are different. Complex 1 crystallizes in cyclic metal-radical dimer consisting of four Cu(hfac)2 and two NIT-4PyPh ligands; four Cu(II) atoms adopt two coordinated modes. In the ring, each Cu(II) ion is hexa-coordinated by four oxygen atoms of two hfac ligands and one oxygen atom (ONCNO) and one nitrogen atom of the pyridinyl group from two different radicals. Outside the ring, each Cu(II) is penta-coordinated by four oxygen atoms of two hfac ligands and one oxygen atom (ONCNO) from the radical ligand. Complex 2 crystallizes in discrete molecule, while the Cu(II) atom is hexa-coordinated by four oxygen atoms of two hfac molecules and two nitrogen atoms of the pyridinyl group from two radical ligands.