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http://www.iupac.org/publications/pac/1986/pdf/5807x0955.pdf

has been cited by the following article:

• TITLE: Formulation of Titration Curves for Some Redox Systems

  AUTHORS: Anna M. Michałowska-Kaczmarczyk, Maciej Rymanowski, Agustin G. Asuero, Marcin Toporek, Tadeusz Michałowski

  KEYWORDS: Solution Thermodynamics, Generalized Approach To Electrolytic Systems, Generalized Electron Balance, Redox Titration

  JOURNAL NAME: American Journal of Analytical Chemistry, Vol.5 No.13, September 24, 2014

  ABSTRACT: The formalism realised according to the Generalised Approach to Electrolytic Systems (GATES) is presented and applied to typical redox systems known from the laboratory practice. In any redox system, the Generalized Electron Balance (GEB), perceived as the law of the matter conservation, is derivable from linear combination 2·f(O) – f(H) of elemental balances: f(O) for oxygen and f(H) for hydrogen. It is an equation linearly independent from other (charge and concentration) balances referred to an electrolytic redox system (aqueous media) of any degree of complexity, and named as the primary form of GEB and then denoted as pr-GEB. A compact equation for GEB is obtained from linear combination of 2·f(O) – f(H) with other (charge and concentration) balances. For a non-redox electrolytic system, of any degree of complexity, the balance 2·f(O) – f(H) is not an independent equation. In the derivation of GEB, all known components (species) of the system tested, taken in their real (i.e., hydrated) form, are involved in the balances, and none simplifying assumptions are needed. The redox systems are simulated with use of an iterative computer program.