J. M. J. Fréchet, P. Darling and M. J. Farrall, “Polymeric Reagents V. Preparation of a New Recyclable Polymeric Oxidizing Agent for the Oxidation of Halides and Tosylates into Carbonyl Compounds,” Polymer Preprints, Vol. 21, No. 2, 1980, pp. 270-272.

has been cited by the following article:

• TITLE: Synthesis, Characterization of Cellulose Grafted N-Oxide Reagent and Its Application in Oxidation of Alkyl/Aryl Halides

  AUTHORS: Inderjeet Kaur, Poonam K. Dhiman

  KEYWORDS: Cellulose, 4-vinyl Pyridine, Graft Co-polymerization, Cellulose Supported N-oxide, Oxidation, Thermo-gravimetric Analysis

  JOURNAL NAME: International Journal of Organic Chemistry, Vol.1 No.1, April 2, 2011

  ABSTRACT: Oxidation of aliphatic and aromatic halides by N-oxide functionalities supported on 4- vinyl pyridine, (4-VP), grafted cellulose is reported in the present manuscript. Synthesis of graft copolymer of cellulose and poly 4-vinyl pyridine, poly(4-VP), has been carried out using ceric ions as redox initiator. Post-grafting treatment of CellO-g-poly (4-VP) with 30% H2O2 in acetic acid gives Cellulose-g-poly (4-VP) N-oxide, the polymeric supported oxidizing reagent. The polymeric support, CellO-g-poly (4-VP) N-oxide, has been used for oxidation reactions of different alkyl / aryl halide such as 1-bromo-3-methyl butane, 2-bromo propane,1-bromo heptane and benzyl chloride. The polymeric reagent was characterized by IR and thermo-gravimetric analysis. The oxidized products were characterized by FTIR and H1NMR spectral methods. The reagent was reused for the oxidation of a fresh alkyl / aryl halides and it was observed that the polymeric reagent oxidizes the compounds successfully but with little lower product yield.