Huang, J.M. and Yang, S.J. (2005) Studying the Miscibility and Thermal Behavior of Polybenzoxazine/Poly(ε-Caprolactone) Blends Using DSC, DMA, and Solid State 13C NMR Spectroscopy. Polymer, 46, 8068-8078.
http://dx.doi.org/10.1016/j.polymer.2005.06.104

has been cited by the following article:

• TITLE: Development of Polycaprolactone/Poly(Vinyl Alcohol)/Clay Microparticles by Spray Drying

  AUTHORS: Mariana Sato de S. de B. Monteiro, Claudia Lopes Rodrigues, Eduardo Miguez, Maria Inês B. Tavares

  KEYWORDS: Microparticles, Spray Drying, Polycaprolactone, Poly(Vinyl Alcohol), Sodium Clay NT-25

  JOURNAL NAME: Materials Sciences and Applications, Vol.7 No.10, September 30, 2016

  ABSTRACT: In this study, nanostructured microparticles was developed with polycaprolactone (PCL), poly(vinyl alcohol) (PVAL) and nanoparticles of the commercial sodium clay NT-25® by using the spray drying technique. The systems obtained were characterized by Nuclear Magnetic Resonance (NMR), Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Dynamic Laser Light Scattering (DLS) and Differential Scanning Calorimetry (DSC). The NMR 13C and FTIR techniques showed that both polymers were present in the microparticles and the DSC analysis revealed a small variation in the glass transition temperature of the PCL. The XRD and SEM analyses showed that the microparticles produced were amorphous and had a concave morphology. The NT-25 nanoload reduced the microparticles’ size due to the multiple interactions formed in the hybrid nanocomposite material. Therefore, it was possible to develop microparticles by using biodegradable and biocompatible polymers, with different polarities, allowing the incorporation of hydrophilic and hydrophobic materials and enabling the inclusion of otherwise incompatible materials in the same system.