TITLE:
Generalized Electron Balance for Dynamic Redox Systems in Mixed-Solvent Media
AUTHORS:
Anna Maria Michałowska-Kaczmarczyk, Tadeusz Michałowski
KEYWORDS:
Electrolytic Redox Systems, Generalized Electron Balance, Mixed-Solvent Media
JOURNAL NAME:
Journal of Analytical Sciences, Methods and Instrumentation,
Vol.4 No.4,
December
2,
2014
ABSTRACT: A complex example of electrolytic redox system involving 47 species, 3 electron-active elements and five (3 am-phiprotic + 2 aprotic) co-solvents, is presented. Mixed solvates of the species thus formed are admitted in the system considered. It is proved that the Generalized Electron Balance (GEB) in its simplest form obtained according to the Approach II to GEB is identical with the one obtained for aqueous media and binary-solvent system, and is equivalent to the Approach I to GEB.