^{1}

^{*}

^{2}

Bulk materials were synthesized by the Bridgman technique using the elements Cu, In and Se. These samples were characterized by Energy Dispersive Spectrometry (EDS) to determine the elemental composition, as well as by X-ray diffraction for structure, hot point probe method for type of conductivity, Optical response (Photoconductivity) and Photoluminescence (PL) to determine the band gap value and Spectroscopic Ellipsometry to find energy levels above the gap in the band scheme at room-temperature. They show a nearly perfect stoechiometry and present a p-type conductivity. CuIn
_{3}Se
_{5} either has a Stannite structure, an Ordered Defect Chalcopyrite structure (ODC), or an Ordered Vacancy Chalcopyrite structure (OVC). The gap energy obtained for the different samples was 1.23 eV. Energy levels above the gap in the band scheme were determinate by measuring the dielectric function at room temperature for energies lying between 1.5 and 5.5 eV. Many transitions were observed above the gap for different samples. Spectroscopic Ellipsometry gave evidence for the interpretation of the choice of gap values which were compatible with that obtained from solar spectrum.

CuIn_{1−x}Ga_{x}Se_{2} semiconductor compounds with chalcopyrite structure are good candidates for absorbers in high-efficiency photovoltaic devices. Some studies have shown that higher efficiency was reached in samples where a Cu(In_{1−x}Ga_{x})_{3}Se_{5} phase was formed at the surface of the CuIn_{1−x}Ga_{x}Se_{2} layer [_{3}Se_{5}, generally possess wider band gap and the formation of ternary Cu-In-Se compounds enables the formation of hetero-junctions used in the design of high-performance electronic and optoelectronic devices. Therefore, CuIn_{3}Se_{5} has been of interest to many groups [_{3}Se_{5} were grown by the horizontal Bridgman methods [^{−6} Torr. Energy Dispersive Spectrometer (EDS) and X-ray diffraction (XRD) were used to calculate the compositions of the ingots considered as very important parameters. The hot point probe method is used in order to determine the conduction types of these ingots; Photoconductivity (PC) and Photoluminescence (PL) allowed us to check their optical properties. Spectroscopic Ellipsometry (SE) is used to determine the energy levels above the gap in the band scheme at room temperature. Spectroscopic Ellipsometry (SE) technique is an experimental tool for measuring simultaneously the real and imaginary parts of the dielectric function versus photon energy for any semiconductor. The critical point structures in the dielectric function of a semiconductor are due to the optical-point transitions between valence and conduction bands where there exists a large joint density of states, thus providing valuable information on the electronic energy-band structure of the material. The paper proposed a new method used for determining with precision the optical transition that occurred in semiconductor, obtained from the experimental results of (SE). A harmonic oscillator approximation (HOA) was fitted to data for monocrystal silicon and CuIn_{3}Se_{5}. Room-temperature measurements were reported for the-pseudo dielectric function áεñ at energies from 1.5 to 5.5 eV.

Crystals with different compositions were synthesized by direct combination of high purity 5 N for Cu and In and 6 N for Se in the desired proportions. The elements were placed in a quartz tube sealed under a vacuum of 5 × 10^{−6} Torr. This tube was placed in a horizontal heater that reached a temperature exceeding the melting point of the compound. It was left in the heater for 72 hours at which point it was allowed to slowly cool down [

・ a source (75 watt xenon arc lamp) having a sufficiently high light intensity in the spectral range (λ from 0.2 μm to 1 μm), with a high stability (±0.2%). The lamp arc is very short (F » 0.3 mm) and can achieve a well-collimated beam.

・ a monochromator of H10D type, manufactured by Jobin Yvon in holographic gratings. It covers the spectral range 200 - 800 nm with a maximum resolution of 0.5 nm.

・ a polarizer and an analyzer used in the range of 220 nm to 3000 nm, with extinction rates of 10^{−5}. They are mounted on rotating turntables with an accuracy of one minute.

・ a photo-elastic modulator and a photomultiplier (Hamamatsu, F = 12 mm).

In _{3}Se_{5} materials by EDS are presented. The samples show a nearly perfect stoechiometry since the magnitude of deviation from stoechiometry, Dy ( Δ y = ( 3 × Cu ) / In − 1 ), is very small [_{3}Se_{5} sample have a large value of Dy (0.3). A detailed analysis is done in order to study the secondary phases that appear in this sample which will be discussed later on. The CuIn_{3}Se_{5} samples present a n-type conductivity.

The spectra of different CuIn_{3}Se_{5} samples obtained by X-ray diffraction are shown in _{2} compounds, the CuIn_{3}Se_{5} compounds do not have a chalcopyrite structure [

CuIn_{3}Se_{5} | |||||
---|---|---|---|---|---|

Samples | % Cu | % In | % Se | Dy | Conductivity type |

A | 11.2 | 32.4 | 56.4 | +0.037 | n |

B | 11.3 | 32.9 | 55.8 | +0.030 | n |

C | 11.2 | 32.5 | 56.3 | +0.034 | n |

The a and c lattice parameters of CuIn_{3}Se_{5} have been calculated from the spectra where a = 5.76, c = 11.52. These values of a and c are in agreement with those reported in G. Marin et al. and T. Negami et al. [

_{3}Se_{5} obtained at 4.2 K. The spectrum shows the exciton position which is required to determine the gap value of 1.23 eV [

We have determined the band gap energy value by analyzing our samples using spectral Photoconductivity [^{2} as a function of hν) of CuIn_{3}Se_{5}. This spectrum denotes high speeds of surface recombination. A saturation level at high energy was not observed. In these cases, the gap value is given by an approximate value which was found by taking the abscissa of each curve at PC_{max}/2 [

a) Method

Spectroscopic Ellipsometry (SE) is a characterization technique which allows the determination of energy levels above the gap in the band scheme. The real part of the dielectric pseudo-function 〈 ε r 〉 is related to the substrate densities of state D n . The calculation of the 3^{rd} order derivative of the quantity E 2 ε r ( E ) [

D n ( E ) = 1 E 2 d 3 d E 3 [ E 2 ε r ( E ) ]

where E = ℏ ω is the photon energy, allows the determination of the energy levels of optical transitions that correspond to the peaks of D_{n}. In order to illustrate this fact, a harmonic oscillator model, centred at the frequency ω 0 is used. Its’ Lorentz nature is characterized by an elastic amplitude α e and an absorption one α a :

α e = ω 0 2 − ω 2 ( ω 0 2 − ω 2 ) 2 + r 2 ω 2

α a = r 2 ω 2 ( ω 0 2 − ω 2 ) 2 + r 2 ω 2

where r is the damping constant.

α e and α a functions are shown in ^{rd} and 4^{th} order derivatives of functions α e and α a are respectively calculated. The numerical calculation of the n^{th} derivative is made by repeating n times the standard algorithm of the derivative calculation using three points, which is expressed as:

f ′ ( x i ) = f ( x i + 1 ) − f ( x i − 1 ) 2 Δ x

^{th} order derivative. ^{rd} order derivative. In the 2 cases, ω 0 value was determinate. The function α a ( ω ) presents a narrow peak which permit to determine ω 0 with precision. The peaks fineness in the α a ( ω ) 4^{th} derivative and in the α e ( ω ) 3^{rd} derivative spectra, respectively (Full Width Half Maximum (FWHM) lower than that of the initial function), shows that this method is a great way to determine the ω 0 position.

To verify the accuracy of the determination of E_{1}, E_{2}... levels, this method was applied to the case of Si. ε i and ε r represent α e and α a type for each harmonic oscillator, where the energy level is an optical transition described in the band scheme. The spectra of ε_{i} and ε_{r} functions are shown in

The maximum 3^{rd} and 4^{th} order derivatives of ε r and ε i are shown in _{1} (3.6 eV), E_{2} (4.2 eV), and E_{3} (5 eV) are identical to those found by Aspnes et al. [

b) Case of CuIn_{3}Se_{5}

CuIn_{3}Se_{5} samples were characterized by Spectroscopic Ellipsometry, and the observed transitions were determined by the method described above. The different spectra of the imaginary part (ε_{i}) and the real part (ε_{r}) respectively of the dielectric function, for different CuIn_{3}Se_{5} samples are shown in ^{rd} and 4^{th} order derivatives of ε r and ε i respectively, of one sample of CuIn_{3}Se_{5}.

Zeaiter et al. [_{i}) of CuInSe_{2} evolves for different values of Cu/In ratio. In fact the peaks widen when the percentage of indium is increased, because the dielectric function is directly related to the crystal structure. Since the crystal is rich in In, involves a disorder in the crystal lattice and a loss of crystallinity which proved more significantly for high energies. This effect was observed in the case of silicon [_{i}). We noticed the same effects on our spectra of CuIn_{3}Se_{5}.

Samples | E_{1} (eV) | E_{2} (eV) | E_{3} (eV) |
---|---|---|---|

A | 2.75 | 3.68 | 4.62 |

B | 2.73 | 3.70 | 4.64 |

C | 2.75 | 3.69 | 4.61 |

_{1}, E_{2} and E_{3}) for different samples A, B and C. The transitions E_{1} and E_{3} can be attributed to the d levels ionization of Cu. In contrary, the transition E_{2} is related to the hybridization s-s between the s-levels of In and that of Cu. The highest levels of the valence band are essentially constituted by the 4p levels of Se and the d-levels of high density localized of Cu.

Samples of CuIn_{3}Se_{5} have been prepared by the Bridgman method. The different samples have then been characterized by several techniques (EDS, XR, hot point probe, photoluminescence, Photoconductivity and Spectroscopic Ellipsometry). Our samples present good stoechiometry and are well crystallized. Their lattice parameters a = 5.76, and c = 11.52 are similar to those in previous publications, specifically c/a » 2. The CuIn_{3}Se_{5} samples present p-type conductivity. The characterization by photoluminescence and Photoconductivity allowed the gap value of 1.23 eV to be determined for these compounds. The characterization by Spectroscopic Ellipsometry allowed the determination of energy levels above the gap in the band scheme. This study made possible the preparation of a more efficient hetero-junction based on CuIn_{3}Se_{5}.

Habib, D. and El Haj Moussa, G. (2017) Identification of Optical Transitions by Spectroscopic Ellipsometry (SE) on CuIn_{3}Se_{5} Bulk Compounds. World Journal of Condensed Matter Physics, 7, 111-122. https://doi.org/10.4236/wjcmp.2017.74010