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http://dx.doi.org/10.1021/cm00030a013

has been cited by the following article:

• TITLE: Semi-Quantitative Estimation of Ce3+/Ce4+ Ratio in YAG:Ce3+ Phosphor under Different Sintering Atmosphere

  AUTHORS: Lianming Wang, Liqiang Zhuang, Hao Xin, Yuexia Huang, Deqiang Wang

  KEYWORDS: YAG:Ce3+ Phosphor, Semi-Quantitative Estimation, Luminescence, Ratio of Ce3+/Ce4+, XPS, Reduction Atmosphere

  JOURNAL NAME: Open Journal of Inorganic Chemistry, Vol.5 No.1, January 8, 2015

  ABSTRACT: In order to confirm the relationship between the luminescence and the ratio of Ce3+/Ce4+ more clearly, a series of YAG:Ce3+ (Yttrium Aluminum Garnet, Y2.94Al5O12:0.06Ce3+) phosphors were pre- pared under different sintering atmosphere. A semi-quantitative analysis based on X-ray photoe-lectron spectroscopy (XPS) was introduced to study the mole ratio of Ce3+/Ce4+ in the as-synthesized YAG:Ce3+ phosphors. The results indicated that the percentage of Ce3+/(Ce3+ + Ce4+) reached 88.46% under the reduction atmosphere. The emission intensity of YAG:Ce3+ phosphors was in-creased significantly with the increasing of Ce3+ concentration.