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has been cited by the following article:

• TITLE: Thermal Stability and Decomposition Kinetics of Polysuccinimide

  AUTHORS: Li Zhang, Mingxing Huang, Cairong Zhou

  KEYWORDS: Polysuccinimide; Thermal Gravimetric Analysis; Thermal Stability; Decomposition Kinetics

  JOURNAL NAME: American Journal of Analytical Chemistry, Vol.4 No.12, December 16, 2013

  ABSTRACT: The thermal stability and decomposition kinetics of polysuccinimide (PSI) were investigated using analyzer DTG-60 under high purity nitrogen atmosphere at different heating rates (3, 6, 9, 12 K/min). The thermal decomposition mechanism of PSI was determined by Coats-Redfern method. The kinetic parameters such as activation energy (E), pre-exponential factor (A) and reaction order (n) were calculated by Flynn-Wall-Ozawa and Kissinger methods. The results show that the thermal decomposition of PSI under nitrogen atmosphere mainly occurs in the temperature range of 619.15-693.15 K, the reaction order (n) was , the activation energy (E) and pre-exponential factor (A) were obtained to be 106.585 kJ/mol and 4.644 × 109 min-1, the integral and differential forms of the thermal decomposition mechanism of PSI were found to be and , respectively. The results play an important role in understanding the thermodynamic properties of polysuccinimide.