TITLE:
Metal Salt and Non-Electrolyte Separation by Means of Dialysis through the Composite Membranes
AUTHORS:
Elena Butyrskaya, Natalia Belyakova, Ludmila Nechaeva, Lubov Zolotaryova, Vladimir Shaposhnik, Vladimir Selemenev
KEYWORDS:
Membranes, Composite Membranes, Electrolytes, Non-Electrolytes, Separation, Sodium Chloride, Potassium Chloride, Ethylene Glycol
JOURNAL NAME:
American Journal of Analytical Chemistry,
Vol.7 No.5,
May
19,
2016
ABSTRACT: To separate salts of metals and non-electrolytes, the approach of dialysis through the composite membranes (CMs) is proposed. CM is a combination of cation and anion exchange areas. In the composite membrane, cations and anions are transferred through the respective exchange areas simultaneously without violation of macroscopic electro-neutrality. This provides a better transfer of salts than conventional ion exchange membranes (IEMs). The dialysis of the ethylene glycol aqueous salt solutions through the CMs was investigated. We have shown that the transport of salts through the composite membranes is more intensive (unlike IEM providing no transfer of salts from weakly mineralized aqueous solutions due to the Donnan exclusion) and the ethylene glycol transfer is not very significant, that is the basis of effective separation. The possibility to use of composite membranes for metal salt and other electrolyte separation is discussed.