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Crystal Data for cis-[(CpMo(CO)2{S2C-N(CH2)5}]: Empirical Formula C13H15MoNO2S2, MW = 377.32, Triclinic, Space groupP1, a = 6.449(7) A, b = 10.634(10) A, c = 11.383(12) A, α = 71.94(3)°, β = 82.31(3)°,γ = 76.43(3)°, V =719.9(13) A3, T= 273(2) K, Z= 2, μ=1.197 mm-1, F(000) 380, density (calculated) 1.741 Mg/m3, 7722 Reflections Collected, 3303 Independentreflections [R(int) = 0.0477]. The Final R1 = 0.0486, wR2 = 0.1288 [I > 2σ (I)], R Indices (all data) R1 = 0.0719, wR2 = 0.1566.
has been cited by the following article:
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TITLE:
Dicyclopentamethylenethiuram Disulfide as Precursor of Mononuclear Complexes: Oxidative Cleavage of Metal-Metal Bond in [CpMo(CO)3]2 and Molecular Structure of cis-[CpMo(CO)2{S2C-N(CH2)5}]
AUTHORS:
Md. Manzurul Karim, Shafikul Islam, Md. RafikulIslam, Mohammad R. Karim, Tasneem A. Siddiquee
KEYWORDS:
Dicyclopentamethylenethiuram Disulfide (Dcpmtd), Oxidation Number, Oxida-tive Cleavage, Coordination Number, Mononuclear Complex, X-Ray Crystal Structure
JOURNAL NAME:
Crystal Structure Theory and Applications,
Vol.6 No.4,
November
30,
2017
ABSTRACT: The reaction of [CpMo(CO)3]2 with dicyclopentamethylenethiuram disulfide in refluxing xylene resulted a novel mono nuclear complex,
cis-[(CpMo(CO)2{S2C-N(CH2)5}] as red crystals in moderate yield. The compound was formed by the oxidative cleavage of metal-metal bond in [CpMo(CO)3]2 together with a reductive sulfur-sulfur bond scission in the ligand.