Aging Behaviours of 8011 Al and 8011 Al/15% SiCp Composites

In this investigation, the effect of aging on the hardness and tensile behavior of 15% SiCp/8011 Al composites has been studied. The composites were manufactured through stir casting method. Cast ingots of the composites were hot extruded at 500˚C. The composite samples were solution heat-treated at 530˚C for 3 h and quenched in cold water. The aging temperature was 130˚C, 150˚C, 170˚C, 190˚C, and 210˚C for aging duration of 1, 3, 5, 7 and 9 hrs respectively. The mechanical properties measured included: tensile strength, yield strength and hardness values. The composites produced exhi-bited maximum mechanical properties at peak aged condition. These in-creases in mechanical properties during aging are attributed to the formation of coherent and uniform distribution SiC particles in the aluminum matrix composites. It was also observed that thermal modification plays an impor-tant role in retaining the ductility of composites. This result shows that a sub-stantial improvement in mechanical properties has been achieved in the reinforced metal matrices produced after age-hardening.


Introduction
The 2xxx, 6xxx, 7xxx and 8xxx aluminium alloys have been used widely as matrix materials for making composites. For good bonding and strength in the composites, metal alloys are used as the matrix element instead of pure metals.
Aluminium alloys containing reactive elements like Mg, Li which normally aid interfacial bonding with the dispersions, will be ideal as the matrix material. In general, Al-Cu-Mg (2xxx) matrix system provides excellent combination of strength and damage tolerance. While Al-Zn-Mg-Cu (7xxx) matrix system can offer higher strength potential Al-Mg-Si-Cu (6xxx) system provide improved corrosion resistance for severe environments as well as improved product fabric ability. With high strength to weight ratio of (8xxx) aluminium and its alloy, based on the Al-Li-Cu-Mg system, the mechanical properties are closely related to the microstructure of these alloys, which are greatly influenced by thermo mechanical processing. The age hardening characteristics of an alloy are generally modified by the introduction of reinforcement. These modifications are due to the manufacturing process, the reactivity between the reinforcement and matrix, the size, the morphology and the volume fraction reinforcement [1]. A great deal of research has been carried out in the past to develop and improved aluminum based composites with the aim of achieving better mechanical properties. In general many techniques have been developed to fabricate the SiC particle reinforced aluminium alloy composite, including casting, powder metallurgy, molten metal methods, pressure infiltration and spray deposition. Among all the fabrication method, the stir casting technique is attractive because it offers uniform distribution reinforcement, flexibility and applicability to large quantity production [2]. These composites are the typical candidates for engineering application in aerospace, military, civil and manufacturing industry. Borrego et al. [3] studied the influence of extraction temperature on the aging behaviour of 6061 Al-15% SiC w composites and reported that accelerated aging observed in composite materials with respect to the unreinforced alloy is more accentuated with increasing extraction temperature. This is described to the increasing dislocation density of the composites since fragmentation of whiskers during consolidation is reduced with extraction temperature. Qureshi et al. [4] developed a mathematical model to predict the mechanical model to predict the mechanical properties of aluminium alloys subjected to prediction hardening. The model, based on the experimental data, was used to predict the tensile strength and yield strength as the response of aluminium alloys subjected to age-hardening process.
No much is documented on the age hardening characteristics of this alloy particularly with silicon carbide reinforcement. Hence the need for research in this area is justified. The objective of this present research therefore is to study the age hardening characteristics of 15% SiCp/8011 Al particulate composites [5].

Results and Discussion
In the following sections, the microstructure, effect of solution zing time, effect of aging temperature and time on tensile behavior of the materials examined are presented.

1) Micro hardness of the composites as a function of aging time
In this paper the effect of aging temperature and time on the precipitation process has been studied. The sequence of operations is involved are solutionizing at 530˚C for 3 hours quenching and artificially aging at different temperatures (130˚C to 210˚C) over time period for 1 -9 hours. The specimens were then tested for microhardness and the results were presented in Figure 1. From the results it is found that the microhardness of the specimen subject to 5 hours aging time is superior than to those subjected to 1 hour to 4 hours aging time.
Moreover, it is also seen that aging time of 6 hours to 8 hours does not result in appreciable improvement in the hardness compared to hardness achieved for 5 hours aging time. Hence, aging time of 5 hours is inferred to be optimum for AA 8011-SiCp composites [6]. The increase the hardness of the composite at under aged and peak aged stage is attributed to the formation of the: G.P zone of the ø' phase, due to the higher rate of decomposition as a result of the presence of dislocation, which are considered favorable sites for nuclei formation. The more deformation, the higher dislocation density, and hence the faster the precipitation. This could explain the early appearance of the peak hardness. The decrease of the hardness of the composite at over aged condition, both discontinuous and continuous precipitates became coarser [7].
In the under aged condition 1 hour at 130˚C, the tensile strength 8011 Al/15% SiCp composite is increased from 139 Mpa to 159 Mpa respectively. It is obvious that plastic deformation of the mixed soft metal matrix and non deformable reinforcement is more difficult than base metal itself [8]. The load bearing capacity of the hard particles as well as higher dislocation density of the matrix due to the thermal mismatch between the aluminum alloy and the reinforcement are response to the higher strength obtained.
In the peak aged condition 5 hour at 170˚C, the tensile strength increased from 159 Mpa to 257 Mpa as shown in Figure 2. From this value, it is inferred that the tensile strength of the composites are greater than those of the aluminum base alloy. Because of the SiC particle provides more interface area, which serves as the nucleation site for grain formation during stir casting and as a barrier for grain growth during heat treatment therefore, it is not generally surprising that decreasing the grain size of the reinforcement, in addition to the effect of less intercept length between SiC particles (SiC particles exert more restriction on plastic flow during deformation) as well as a higher dislocation density of metal matrix, results in higher tensile strength [9].
In over aged condition 9 hour at 210˚C, the tensile strength decreased from 257 Mpa to 189 Mpa. Then the volume fraction of the precipitates remain constant, and the interspacing of the precipitates increase if the aging time and temperature continues to increase through the growth of larger precipitates and the dissolving of the smaller precipitates. The increase in the interspacing of the precipitates will decrease strength [10].

4) Fractography
The fracture surface of the composite in the extruded condition is shown in Figure 4. The fracture surfaces of the composite after extrusion include mainly ductile dimples of the matrix and particle fracture, Indicating an enhanced interfacial bonding strength and mechanical properties. The distribution of reinforcement was uniform [12]. Figure 5 shows the SEM fractograh of 8011 Al/15% SiC composites in their under aged condition (1 hour at 130˚C). The fracture surface of composites reveal two operating fracture mechanisms: micro-void formation and SiC particle cracking [13]. Figure 6 shows the SEM fractograh of 8011 Al/15% SiC composites in their peak aged condition (5 h at 170˚C). The fracture surface of composites revealed the coexistence of ductile and cleavage fracture [14]. Al/15% SiC composite. The results of SEM examination of over aged (9 h at 210˚C) composite also revealed the presence of fractured particulates as well as some interfacial de-bonding [15]. The increase in the interfacial de-bonding will decrease the tensile strength. A typical fractograph is shown Figure 7.

Conclusion
In the peak aged condition 5 hours at 170˚C, the tensile strength increased from 159 Mpa to 257 Mpa. From this value, it is inferred that the tensile strength of the composites is greater than those of the aluminum base alloys. Because of the SiC particle provides more interface area, which serves as the nucleation site for grain formation during stir casting and as a barrier for grain growth during heat treatment; therefore, it is not generally surprising that decreasing the grain size of the reinforcement, in addition to the effect of less intercept length between SiC particles (SiC particles exert more restriction on plastic flow during deformation) as well as a higher dislocation density of metal matrix, results in higher tensile strength.

Conflicts of Interest
The author declares no conflicts of interest regarding the publication of this paper.