Structural and Optical Properties of Li+: PVP & Ag+: PVP Polymer Films
Kothapalle Sivaiah, Koramala Naveen Kumar, V. Naresh, Srinivasa Buddhudu
DOI: 10.4236/msa.2011.211225   PDF    HTML     8,822 Downloads   16,656 Views   Citations


PVP polymers containing Li+ or Ag+ Ions have been synthesized in good stability and transparency by using the solution casting method. Their structural, optical, thermal and electrical properties have been investigated from the measurement of XRD, FTIR, SEM, EDAX, optical absorption spectra, TG-DTA profiles and impedance spectral features in order to evaluate their potentialities for their use in electrochemical display device applications.

Share and Cite:

K. Sivaiah, K. Kumar, V. Naresh and S. Buddhudu, "Structural and Optical Properties of Li+: PVP & Ag+: PVP Polymer Films," Materials Sciences and Applications, Vol. 2 No. 11, 2011, pp. 1688-1696. doi: 10.4236/msa.2011.211225.

Conflicts of Interest

The authors declare no conflicts of interest.


[1] M. J. Reddy, S. S. Rao, E. L. and U. V. S. Rao, “Study of a Thin Film Electrochemical Cell Based on (PVP + AgNO) Electrolyte,” Solid State Ionics, Vol. 80, No. 1-2, 1995, pp. 93-98. doi:10.1016/0167-2738(95)00128-S
[2] Z. T. Rui, L. Ran, L. L. Xin, Z. Y. Ying, L. T. Jin and Y. J. Nian, “Photochromic Polyoxotungstoeuropate K12 [Eu P5W30O110]/Polyvinylpyrrolidone Nanocomposite Films,” Journal of Solid State Chemistry, Vol. 172, No. 2, 2003, pp. 458-463. doi:10.1016/S0022-4596(03)00036-7
[3] C. S. Ramya, S. Selvasekarapandian, G. Hirankumar, T. Savitha and P. C. Angelo, “Investigation Sonthe Effect of Complexation of NaFsalt with Polymerblend (PEO/PVP) Electroly Tesonionic Conductivity and Optical Energybandgaps,” Journal of Non-Crystal Solids, Vol. 354, 2008, pp. 1494-1502. doi:10.1016/j.jnoncrysol.2007.08.038
[4] J. Zhang, H. Liu, Z. Wang and N. Ming, “Low-Tempera- ture Growth of ZnO with Controllable Shapes and Band Gaps,” Journal of Crystal Growth, Vol. 310, No. 11, 2008, pp. 2848-2853. doi:10.1016/j.jcrysgro.2008.02.014
[5] H. Fatima, T. Sandrine, M. Gilles and G. Jean-Luc, “Photooxidation of Poly (N-vinylpyrrolidone) (PVP) in the Solid State and in Aqueous Solution,” Polymer Degradation and Stability, Vol. 94, No. 12, 2009, pp. 2257- 2266. doi:10.1016/j.polymdegradstab.2009.08.007
[6] Y. Kobayashi, A. Kosuge and M. Konno, “Fabrication of High Concentration Barium Titanate/Polyvinylpyrroli- done Nano-composite Thin Films and Their Dielectric Pro- perties,” Applied Surface Science, Vol. 255, No. 5, 2008, pp. 2723-2729. doi:10.1016/j.apsusc.2008.08.006
[7] C. Hsien-Wei, L. Tzu-Pin and C. Feng-Chih, “Ionic Conductivity Enhancement of the Plasticized PMMA/LiClO4 Polymer Nanocomposite Electrolyte Containing Clay,” Polymer, Vol. 43, No. 19, 2002, pp. 5281-5288. doi:10.1016/S0032-3861(02)00339-7
[8] R. Baskarana, S. Selvasekarapandiana, N. Kuwatab, J. Kawamurab and T. Hattori, “Structure, Thermal and Transport Properties of PVAc–LiClO4 Solid Polymer Electrolytes,” Journal of Physics and Chemistry of Solids, Vol. 68, No. 3, 2007, pp. 407-412.
[9] S. Vaidyanathan, N. Nicholas, E. G. Seebauer, A. Mark, R. Shannon and I. Masel, “Synthesis and Characterization of Polyvinylpyrrolidine Assisted Tantalum Pentoxide Films,” Thin Solid Films, Vol. 516, No. 15, 2008, pp. 4784- 4792. doi:10.1016/j.tsf.2007.08.138
[10] L. Katarzyna, “Miscibility and Interactions in Chitosan acetate/poly (N-vinylpyrrolidone) Blends,” Thermoche- mica Acta, Vol. 517, No. 1-2, 2011, pp. 90-97.
[11] L. Xiaolin, H. Kun, G. Mu, H. Shiming, L. Bo and N. Chen, “Optical Properties of GdTaO4:Eu3+ Thick Films Prepared from a PVP-Containing Solution,” Applied Surface Science, Vol. 255, No. 8, 2009, pp. 4680-4683. doi:10.1016/j.apsusc.2008.12.026
[12] R. Nithya and R. Ragunathan, “Synthesis of Silver Nano- particle Pleurotus Sajor Caju and Its Antimicrobial Study,” Digest Journal of Nanomaterials and Biostructures, Vol. 4, No. 4, 2009, pp. 623-629.
[13] V. P. Ghodake, P. T. Kininge, S. P. Magdum, A. S. Dive and M. M. Pillai, “Bipsynthesis of Silver Nanoparticles Using Trichosporon Beigelii Ncim 3326 and Evaluation of Their,” Journal of Engineering Research and Studies, Vol. 11, No. 1, 2011, pp. 32-36.
[14] L. Manhong, Y. Xiaoping, L. Hanfan and Y. Weiyong, “An Investigation of the Interaction between Polyvi- nylpyrrolidone and Metal Cations,” Reactive & Functional Polymers, Vol. 44, No. 1, 2000, pp. 55-64. doi:10.1016/S1381-5148(99)00077-2
[15] E. K. Elumalai, “Extracellular Synthesis of Silver Nanoparticles Using Leaves of Euphorbia hirta and Their Antibacterial Activities,” Journal of Pharmaceutical Sciences and Research, Vol. 2, 2010, pp. 549-554.
[16] S. S. Gasaymeh, S. Radiman, L. Y. Heng and E. G. H. M. Saion, “Synthesis and Characterization of Silver/Poly- vinilpirrolidone (Ag/PVP) Nanoparticles Using Gamma Irradiation Techniques,” American Journal of Applied Sciences, Vol.7, No. 7, 2010, pp. 892-901. doi:10.3844/ajassp.2010.892.901
[17] Z. Maoping, G. Mingyuan, J. Yanping and J. Guoliang, “Optical Properties of Silver-Dispersed PVP Thin Film,” Materials Research Bulletin, Vol. 36, No. 5-6, pp. 2001, 853-859.
[18] W. Yongzhi, L. Yaoxian, Y. Songtao, Z. Guangliang, A. Dongmin, C. Wang, Y. Qingbiao, C. Xuesi, J. Xiabin and W. Yen, “A Convenient Route to Polyvinyl Pyrrolidone/ Silver Nanocomposite by Electrospinning,” Nanotechnology, Vol. 17, No. 13, 2006, pp. 3304-3307. doi:10.1088/0957-4484/17/13/037
[19] R. Geethalakshmi and D. V. L. Sarada, “Synthesis of Plant- Mediated Silver Nanoparticles Using Trianthema decandra Extract and Evaluation of Their Anti Microbial Activities,” International Journal of Engineering Science and Technology, Vol. 2, No. 5, 2010, pp. 70-975.
[20] W. Hew-Der, W. I-Der and C. Feng-Chih, “The Interaction Behavior of Polymer Electrolytes Composed of Poly(Vinyl Pyrrolidone) and Lithium Perchlorate (LiClO4),” Polymer, Vol. 42, No. 2, 2001, pp. 555-562. doi:10.1016/S0032-3861(00)00213-5
[21] J. Ming, Z. Xintong, N. Shunsuke, L. Zhaoyue, A. T. Donald, M. Taketoshi and F.Akira, “Large-Scale Fabrication of Ag Nanoparticles in PVP Nanofibres and Net-Like Silver Anofibre Films by Electrospinning,” Nanotechnology, Vol. 18, 2007, pp. 1-7.
[22] X. K. Mengy, S. C. Tang and S. Vongehr, “A Review on Diverse Silver Nanostructures,” Journal of Material Science and Technology, Vol. 26, No. 6, 2010, pp. 487-522. doi:10.1016/S1005-0302(10)60078-3
[23] C. Misuk, K. Seulgi, K. Inhoi, K. Byungwoo and L. Youngkwan, “One-Step Synthesis of Polymer-Stabilized Ag Particles on PEDOT: Effects of Stabilizer and Electrochemical Method on Formation of Ag Particle,” Macromolecular Research, Vol. 18, No. 11, 2010, pp. 1070- 1075.
[24] Z. Cui, H. Ren, G. Liu and G. Hong, “Synthesis and Characterization of Terbium-Trimesic Acid Luminescent Complex in Polyvinylpyrrolidone Matrix,” Journal of Rare Earths, Vol. 24, No. 6, 2006, pp. 724-727. doi:10.1016/S1002-0721(07)60016-7
[25] S. G. Shawkat, R. Shahidan, Y. H. Lee and S. Elias, “Gamma Irradiation Synthesis and Influence the Optical and Thermal Properties of Cadmium Sulfide (CdS)/Poly (Vinyl Pyrolidone) Nanocomposites,” American Journal of Applied Sciences, Vol. 7, No. 4, 2010, pp. 500-508. doi:10.3844/ajassp.2010.500.508
[26] M. Prabu, S. Selvesekarpanddian, A. R. Kulkarni, S. Karthikeyan and G. S. Structural, “Dielectric and Conductivity Studies of Yettrium-Doped LiNiPO4 Hirankumar, and C. Anjeevi Raj,” Ionics, Vol. 17, 2011, pp. 201- 207. doi:10.1007/s11581-011-0535-5
[27] D. Supti and J. A. Bhattacharyya, “Dielectric Relaxation Spectroscopy for Evaluation of the Influence of Solvent Dynamics on Ion Transport in Succinonitrile-Salt Plastic Crystalline Electrolytes,” Journal of Physical Chemistry B, Vol. 115, No. 10, 2011, pp. 2148-2154. doi:10.1021/jp108848b
[28] R. J. Sengwa, S. Choudhary and S. Sankhla, “Low Frequency Dielectric Relaxation Processes and Ionic Conductivity of Montmorillonite Clay Nanoparticles Colloidal Suspension in Poly (Vinyl Pyrrolidone)-Ethylene Glycol Blends,” Express Polymer Letters, Vol. 2, No. 11, 2008, pp. 800-809. doi:10.3144/expresspolymlett.2008.93
[29] M. H. Bhat, M. Kandavel, M. Ganguli and K .J. Rao, “Li+ Ion Conductivities in Boro-Tellurite Glasses,” Bulletin of Materials Science, Vol. 27, No. 2, 2004, pp. 189-198. doi:10.1007/BF02708504
[30] M. Vijayakumwr, S. Selvesekarpanddian, D. Jayanthi and R. Kavitha, “Effect of Annealing on Li2O-TiO2-V2O5 Electrolyte Materials,” Solid State Ionics, Vol. 154, 2002, pp. 773-777. doi:10.1016/S0167-2738(02)00703-8

Copyright © 2024 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.