Development of Hydrogel Polyelectrolyte Membranes with Fixed Sulpho-Groups via Radical Copolymerization of Acrylic Monomers


Electrolyte hydrogels are perspective materials for applications in electrochemical devices, which work at ambient temperatures. In this work, hydrogel sulpho-modified membranes were formed by radical co-polymerization of sodium styrensulphonate and potassium sulphopropyl acrylate with acrylamide and acrylonitrile. The hydrogel membranes were obtained in the form of thin films. Properties of the membranes were studied by thermogravimetry, mass-spectrometry and IR-spectrometry. The prepared membranes were thermally stable up to 70°C - 90°C, and showed ion exchange capacity and swelling coefficients sufficient for use as ion-exchange or proton-conducting membranes.

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I. Stadniy, V. Konovalova, Y. Samchenko, G. Pobigay, A. Burban and Z. Ulberg, "Development of Hydrogel Polyelectrolyte Membranes with Fixed Sulpho-Groups via Radical Copolymerization of Acrylic Monomers," Materials Sciences and Applications, Vol. 2 No. 4, 2011, pp. 270-275. doi: 10.4236/msa.2011.24035.

Conflicts of Interest

The authors declare no conflicts of interest.


[1] R. Singh, “Industrial Membrane Separation Processes,” Chemtech, Vol. 28, No. 4, 1998, pp. 33-44.
[2] M. Mulder, “Basic Principles of Membrane Technology,” Kluwer Academic Publishers, Dordrecht, 1996.
[3] Y. Osada, J. Gong and Y. Tanaka, “Polymer Gels,” In: K. Takemoto, R. Ottenbrite and M. Kamachi, Eds., Functional Monomers and Polymers, Marcel Dekker, New York, 1997, p. 497.
[4] S. Chandra, S. Sekhon, R. Srivastava and N. Arora, “Proton-Conducting Gel Electrolyte,” Solid State Ionics, Vol. 154-155, No. 2, December 2002, pp. 609-619. doi:10.1016/S0167-2738(02)00505-2
[5] Y. Wan, K. Creber, B. Peppley and V. Bui “Chitosan-Based Electrolyte Composite Membranes II. Mechanical Properties and Ionic Conductivity,” Journal of Membrane Science, Vol. 284, No. 2, November 2006, pp. 331-338. doi:10.1016/j.memsci.2006.07.046
[6] N. Choudhury, S. Prashant, S. Pitchumanl, P. Sridhar and A. Shukla, “Poly (Vinyl Alcohol) Hydrogel Membrane as Electrolyte for Direct Borohydride Fuel Cells,” Journal of Chemical Sciences, Vol. 121, No. 5, September 2009, pp. 647-654. doi:10.1007/s12039-009-0078-8
[7] M. G. Kodzwa, M. E. Staben and D. G. Rethwisch, “Photoresponsive Control of Ion-Exchange in Leucohydroxide Containing Hydrogel Membranes,” Journal of Membrane Science, Vol. 158, No. 1, June 1999, pp. 85-92. doi:10.1016/S0376-7388(99)00008-3
[8] T. Kasuga, M. Nakano and M. Nogami, “Fast Proton Conductors Derived from Calcium Phosphate Hydrogels,” Advanced Materials, Vol. 14, No. 20, October 2002, pp. 1490-1492. doi:10.1002/1521-4095(20021016)14:20<1490::AID-ADMA1490>3.0.CO;2-M
[9] T. Akamatsu, T. Kasuga and M. Nogami, “Formation of Metaphosphate Hydrogels and Their Proton Conductivities,” Journal of Non-Crystalline Solids, Vol. 351, No. 8-9, April 2005, pp. 691-696. doi:10.1016/j.jnoncrysol.2005.01.066
[10] S. Sampath, N. Choudhury and A. Shukla, “Hydrogel Membrane Electrolyte for Electrochemical Capacitors,” Journal of Chemical Sciences, Vol. 121, No. 5, September 2009, pp. 727-734.
[11] A. M. Valente, A. Ya. Polischuk, V. M. Lobo and G. Geukens, “Diffusions Coefficients of Lithium Chlorite and Potassium Chlorites in Hydrogel Membranes Derived from Acrylamide,” European Polymer Journal, Vol. 38, No. 1, January 2002, pp. 13-18. doi:10.1016/S0014-3057(01)00161-6
[12] W. Wieczorek, Z. Florjanczyk and J. R. Stevens, “Proton Conducting Polymer Gels Based on a Polyacrylamide Matrix,” Electrochimica Acta, Vol. 40, No. 13-14, October 1995, pp. 2327-2330.
[13] J. R. Stevens, W. Wieczorek, D. Raducha and K. R. Jeffrey, “Proton Conducting Gel/H3PO4 Electrolytes,” Solid State Ionics, Vol. 97, No. 1-4, May 1997, pp. 347-358. doi:10.1016/S0167-2738(97)00036-2
[14] W. Wieczorek, P. Lipka, G. ?ukowska and H. Wyci?lik, “Ionic Interactions in Polymeric Electrolytes Based on Low Molecular Weight Poly(Ethylene Glycol)s,” Journal of Physical Chemistry B, Vol. 102, No. 36, September 1998, pp. 6968-6974. doi:10.1021/jp981397k
[15] W. Wieczorek, K. Such, H. Wycilik and J. Pocharski, “Modifications of Crystalline Structure of Polymer Electrolytes with Ceramic Additives,” Solid State Ionics, Vol. 36, No. 3-4, September 1989, pp. 255-257. doi:10.1016/0167-2738(89)90185-9
[16] A. M. A. da Costa and A. M. Amado, “Cation Hydration in Hydrogelic Polyacrylamide-Phosphoric Acid Network: A Study by Raman Spectroscopy,” Solid State Ionics, Vol. 145, No. 1-4, December 2001, pp. 79-84. doi:10.1016/S0167-2738(01)00916-X
[17] M. M. Nasef and E.-S. A. Hegazy, “Preparation and Applications of Ion Exchange Membranes by Radiation-Induced Graft Copolymerization of Polar Monomers onto Non-Polar Films,” Progress in Polymer Science, Vol. 29, No. 6, June 2004, pp. 499-561. doi:10.1016/j.progpolymsci.2004.01.003
[18] M. Gertsyuk and Yu. Samchenko, “Separation of Nonreacted Acrylamide from Polyacrylamide Gel for Endoprothesing,” Ars Separatoria Acta, Vol. 5, 2007, pp. 98-101.

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